cobalt tetra-4-benzoylaminotetra-5-nitrophthalocyanine | 438491-93-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cobalt tetra-4-benzoylaminotetra-5-nitrophthalocyanine
• 英文别名: CoPc(4-NHC(O)C6H5)4(5-NO2)4
• CAS: 438491-93-1
• 化学式: C₆₀H₃₂CoN₁₆O₁₂
• 分子量: 1228.01
• InChiKey: NWIZVDMUOPQYGD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  钴 、 4-benzoylamino-5-nitrophthalodinitrile 以 neat (no solvent) 为溶剂， 生成 cobalt tetra-4-benzoylaminotetra-5-nitrophthalocyanine
  参考文献：
  名称：

  Bifunctional octasubstituted phthalocyanines. Synthesis and properties

  摘要：

  Data on the synthesis of bifunctional octasubstituted phthalocyanines are reported. Some specificities of their electronic absorption spectra, thermal stability, and other properties, depending on the substituent nature and central metal ion, are revealed.

  DOI：

  10.1134/s1070363207010215

文献信息

• ——
  作者：M. A. Zharnikova、A. E. Balakirev、V. E. Maizlish、G. P. Shaposhnikov

  DOI：10.1023/a:1015370001651

  日期：——

  The reaction of 4-acylamino-5-nitrophthalocyanines with cobalt(II) chloride was used to prepare for the first time the corresponding cobalt phthalocyanines, Hydrolysis of cobalt(II) tetra-4-acetylamino-tetra5-nitrophthalocyanine gave cobalt(II) tetra-4-aminotetra-5-nitrophthalocyanine. The effect of amino(acylamino) and nitro groups on the properties of the metal complexes, particularly on their electronic absorption spectra, was demonstrated.