2-(hexyloxy)vinyl benzene | 69520-19-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(hexyloxy)vinyl benzene
• 英文别名: [(E)-2-hexoxyethenyl]benzene
• CAS: 69520-19-0
• 化学式: C₁₄H₂₀O
• 分子量: 204.312
• InChiKey: OYZWFFFNQPNZRD-ACCUITESSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(hexyloxy)vinyl benzene 、 2,4-二硝基苯肼 、 高氯酸 以100%的产率得到
  参考文献：
  名称：

  JULIA M.; KIGHINI A.; UGUEN D., J. CHEM. SOC. PERKIN TRANS., 1978, PART 1, NO 12, 1646-1651

  摘要：

  DOI：
• 作为产物：
  描述：

  反式苯基肉桂砜 、 sodium hexanolate 以60%的产率得到
  参考文献：
  名称：

  JULIA M.; KIGHINI A.; UGUEN D., J. CHEM. SOC. PERKIN TRANS., 1978, PART 1, NO 12, 1646-1651

  摘要：

  DOI：

文献信息

• [EN] ENOL ETHER PROPERFUME<br/>[FR] PRO-PARFUM D'ÉNOLÉTHER
  申请人：FIRMENICH & CIE

  公开号：WO2019243501A1

  公开（公告）日：2019-12-26

  The present invention relates to compounds of formula (I) as properfume compounds. In particular, the present invention relates to a method to release a compound being a ketone or aldehyde of formula (II), a formate ester of formula (III) and/or an alcohol of formula (IV) by exposing the compound of formula (I) to an environment wherein it is oxidized. Moreover, the present invention relates to a perfuming composition and a perfume consumer product comprising at least one compound of formula (I).

  本发明涉及化合物的结构式(I)作为香料化合物。具体而言，本发明涉及一种释放结构式(I)化合物的方法，其中该化合物是结构式(II)的酮或醛、结构式(III)的甲酸酯和/或结构式(IV)的醇，通过将结构式(I)的化合物暴露在氧化环境中。此外，本发明涉及一种香水组合物和一种香水消费产品，其中包括至少一种结构式(I)的化合物。
• C−C Bond Formation of Benzyl Alcohols and Alkynes Using a Catalytic Amount of KO^t Bu: Unusual Regioselectivity through a Radical Mechanism
  作者：Amit Kumar、Trevor Janes、Subrata Chakraborty、Prosenjit Daw、Niklas von Wolff、Raanan Carmieli、Yael Diskin-Posner、David Milstein

  DOI：10.1002/anie.201812687

  日期：2019.3.11

  We report a C−C bond‐forming reaction between benzyl alcohols and alkynes in the presence of a catalytic amount of KOtBu to form α‐alkylated ketones in which the C=O group is located on the side derived from the alcohol. The reaction proceeds under thermal conditions (125 °C) and produces no waste, making the reaction highly atom efficient, environmentally benign, and sustainable. Based on our mechanistic

  我们报告一个C-C键形成在催化量KO的存在苄醇类和炔烃之间的反应吨卜以形成α -烷基化的酮，其中C = O基团位于从醇衍生的一侧。该反应在热条件下（125°C）进行，不产生任何废料，使该反应具有较高的原子效率，环境友好性和可持续性。根据我们的机理研究，我们建议反应通过自由基途径进行。
• Polymer for photoresist, method of production thereof and photoresist composition containing polymer
  申请人：——

  公开号：US20020015906A1

  公开（公告）日：2002-02-07

  A polymer for a photoresist composition is given by the formula (I): 1 wherein R 1 is a hydrogen atom or a methyl group, R 2 is a C 1-12 linear or branched alkyl, haloalkyl or alkoxycarbonyl group, a C 5-12 cyclic alkyl, cyclic haloalkyl or cyclic alkoxycarbonyl group, a phenyl group or a naphthyl group, R 3 is a C 1-12 linear or branched alkyl or haloalkyl group, a C 5-12 cyclic alkyl or cyclic haloalkyl group, a phenyl group, or a naphthyl group, R 4 and R 5 are independently a hydrogen atom, a C 1-6 linear or branched alkyl, or a C 5-6 cyclic alkyl group, R′ and R″ are independently a hydrogen atom, a halogen atom, a C 1-8 alkyl or alkoxy group, a hydroxy group, a carbonate group or a phenyl group, and m, n, p and q are independently an integer provided that m and q are not zero, at least one of n and p are not zero, 0.4≦m/(m+n+p+q)≦0.9, 0≦n/(m+n+p+q)≦0.5, 0≦p/(m+n+p+q)≦0.5, and 0.01≦q/(m+n+p+q)≦0.3.

  给出了一种用于光阻组合物的聚合物，其化学式为（I）：其中R1是氢原子或甲基基团，R2是C1-12线性或支链烷基，卤代烷基或烷氧羰基基团，C5-12环烷基，环卤代烷基或环烷氧羰基基团，苯基或萘基，R3是C1-12线性或支链烷基或卤代烷基，C5-12环烷基或环卤代烷基，苯基或萘基，R4和R5分别是氢原子，C1-6线性或支链烷基或C5-6环烷基基团，R'和R"分别是氢原子，卤素原子，C1-8烷基或烷氧基团，羟基，碳酸酯基或苯基，m，n，p和q是整数，其中m和q不为零，n和p中至少有一个不为零，0.4≤m/(m+n+p+q)≤0.9，0≤n/(m+n+p+q)≤0.5，0≤p/(m+n+p+q)≤0.5，0.01≤q/(m+n+p+q)≤0.3。
• IONOMER RESIN AND IONOMER SOLUTION CONTAINING SAME, LAMINATE, MEMBER, ELECTROCHEMICAL ELEMENT, AND ELECTROCHEMICAL DEVICE
  申请人：Nitto Denko Corporation

  公开号：EP3269743A1

  公开（公告）日：2018-01-17

  Provided is an ionomer resin including a copolymer containing the following first structural unit. L1 to L5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is -Z2-M1-Z1(R1)(R2)(R3). R1 to R3 are directly bonded to Z1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z1 is a nitrogen atom or a phosphorus atom, and Z2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L6 is a hydrogen atom, a methyl group, or an ethyl group.

  本发明提供了一种离子聚合物树脂，包括一种含有以下第一结构单元的共聚物。 L1 至 L5 各自独立地为氢原子、具有 1 至 4 个碳原子的烷基、具有 1 至 4 个碳原子的烷醇基或包括阴离子交换基在内的特定官能团，官能团的一个例子是 -Z2-M1-Z1(R1)(R2)(R3)。R1 至 R3 直接与 Z1 键合，各自独立地为具有 1 至 8 个碳原子的烷基或具有 1 至 8 个碳原子的烷醇基。M1 是具有 3 至 8 个碳原子的线性烃链，Z1 是氮原子或磷原子，Z2 是与一个氢原子、氧原子或硫原子键合的氮原子。L6 是氢原子、甲基或乙基。
• Ionomer resin, and ionomer solution, multilayer body, member, electrochemical element, and electrochemical device that include the same
  申请人：NITTO DENKO CORPORATION

  公开号：US10593980B2

  公开（公告）日：2020-03-17

  Provided is an ionomer resin including a copolymer containing the following first structural unit. L1 to L5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is —Z2-M1-Z1(R1)(R2)(R3). R1 to R3 are directly bonded to Z1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z1 is a nitrogen atom or a phosphorus atom, and Z2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L6 is a hydrogen atom, a methyl group, or an ethyl group.

  本发明提供了一种离子聚合物树脂，包括一种含有以下第一结构单元的共聚物。 L1 至 L5 各自独立地为氢原子、具有 1 至 4 个碳原子的烷基、具有 1 至 4 个碳原子的烷醇基或包括阴离子交换基在内的特定官能团，官能团的一个例子是 -Z2-M1-Z1(R1)(R2)(R3)。R1 至 R3 直接与 Z1 键合，各自独立地为具有 1 至 8 个碳原子的烷基或具有 1 至 8 个碳原子的烷醇基。M1 是具有 3 至 8 个碳原子的线性烃链，Z1 是氮原子或磷原子，Z2 是与一个氢原子、氧原子或硫原子键合的氮原子。L6 是氢原子、甲基或乙基。