[MoO(O2)2(morpholinomethylthiourea)] | 924885-64-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧烷类
• 英文名称: [MoO(O2)2(morpholinomethylthiourea)]
• CAS: 924885-64-3
• 化学式: C₆H₁₃MoN₃O₆S
• 分子量: 351.192
• InChiKey: KXDKDWYKTNUJAQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [MoO(O2)2(morpholinomethylthiourea)] 以 neat (no solvent, solid phase) 为溶剂， 生成 molybdenum(IV) oxide
  参考文献：
  名称：

  Synthesis and characterization of some oxodiperoxo molybdenum(VI) complexes of Morpholinomethyl urea and related ligands

  摘要：

  The oxodiperoxo complexes of Mo(VI) of the type [MoO(O-2)(2)L], where L = Morpholinomethyl urea, morpholinomethyl thiourea, piperidinomethyl urea, piperidinomethyl thiourea, pyrrolidinomethyl urea, and pyrrolidinomethyl thiourea have been synthesized and characterized by elemental analysis, molar conductance, IR, UV-Vis, and TGA/DTA techniques. It is shown that the ligands coordinate to the metal ion in a symmetrical bidentate fashion through heterocyclic nitrogen and carbonyl oxygen or thiocarbonyl sulfur. Thermal studies indicate continuous weight loss until a stable oxide is formed.

  DOI：

  10.1134/s003602360605007x
• 作为产物：
  描述：

  ammonium molybdate 、 N-(morpholin-4-ylmethyl)thiourea 、 双氧水 以 乙醇 、 水 为溶剂， 生成 [MoO(O2)2(morpholinomethylthiourea)]
  参考文献：
  名称：

  Synthesis and characterization of some oxodiperoxo molybdenum(VI) complexes of Morpholinomethyl urea and related ligands

  摘要：

  The oxodiperoxo complexes of Mo(VI) of the type [MoO(O-2)(2)L], where L = Morpholinomethyl urea, morpholinomethyl thiourea, piperidinomethyl urea, piperidinomethyl thiourea, pyrrolidinomethyl urea, and pyrrolidinomethyl thiourea have been synthesized and characterized by elemental analysis, molar conductance, IR, UV-Vis, and TGA/DTA techniques. It is shown that the ligands coordinate to the metal ion in a symmetrical bidentate fashion through heterocyclic nitrogen and carbonyl oxygen or thiocarbonyl sulfur. Thermal studies indicate continuous weight loss until a stable oxide is formed.

  DOI：

  10.1134/s003602360605007x