benzoic acid-2,2,2-tris-(diphenylphosphinomethyl)ethylester-molybdenum(0)-tricarbonyl*CH2Cl2 | 156976-88-4

• 英文名称: benzoic acid-2,2,2-tris-(diphenylphosphinomethyl)ethylester-molybdenum(0)-tricarbonyl*CH2Cl2
• CAS: 156976-88-4
• 化学式: CH₂Cl₂*C₅₁H₄₃MoO₅P₃
• 分子量: 1009.69
• InChiKey: IYDDRJDFLPNRKR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(acetonitrile)tricarbonylmolybdenum(0) 、 Benzoesaeure-2,2,2-tris(diphenylphosphinomethyl)ethylester 在 CH₂Cl₂ 作用下， 以 二氯甲烷 为溶剂， 以93%的产率得到benzoic acid-2,2,2-tris-(diphenylphosphinomethyl)ethylester-molybdenum(0)-tricarbonyl*CH2Cl2
  参考文献：
  名称：

  Synthese funktionalisierter tipod-Liganden: Aufbau, Veresterung und Koordinationsfähigkeit von HOCH2C (CH2PPh2)3

  摘要：

  Starting from pentaerythritol, HOCH2C(CH2OH)3, the synthesis of the hydroxy functionalized tripod-ligand HOCH2C(CH2PPh2)3, 4, is achieved in a few steps. Esterification of the hydroxy group of 4 opens a route to the convergent construction of functionalized tripod-ligands R'COOCH2aCH2PR2)3. For ligand 4 and for its benzoyl derivative PhCOOCH2C(CH2PPh2)3, 6, the capability of forming facially coordinated tripod-complexes is verified by the formation of molybdenum and cobalt complexes. The results are documented by the usual analytical techniques as well as by X-ray analyses.

  DOI：

  10.1016/0022-328x(94)88068-9