[bis(2-methyl-2-(salicylaldiminato)-1-oxy-3-hydroxypropane)manganese(IV)] | 106530-85-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [bis(2-methyl-2-(salicylaldiminato)-1-oxy-3-hydroxypropane)manganese(IV)]
• CAS: 106530-85-2
• 化学式: C₂₂H₂₆MnN₂O₆
• 分子量: 469.396
• InChiKey: DVOOOCISVFTZJV-SJNRJLCUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium permanganate 、 2-((2-hydroxybenzylidene)amino)-2-methylpropane-1,3-diol 以 乙腈 为溶剂， 以64%的产率得到[bis(2-methyl-2-(salicylaldiminato)-1-oxy-3-hydroxypropane)manganese(IV)]
  参考文献：
  名称：

  Mn(IV) and Co(III)-complexes of –OH-rich ligands possessing O2N, O3N and O4N cores: syntheses, characterization and crystal structures

  摘要：

  Mn(IV) and Co(III) complexes of tridentate -OH-rich ligands possessing O2N, O3N and O4N donor sets were synthesized, characterized and their structures were established by single crystal X-ray diffraction, where the binding core is O4N2. In the structurally characterized complexes, the coordination geometry about the metal ion was found to be distorted octahedral. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.09.015