3,7-dimethyl-5-phenyl-5H-benzo[b]phosphindole | 69452-61-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,7-dimethyl-5-phenyl-5H-benzo[b]phosphindole
• 英文别名: 3,7-Dimethyl-5-phenylbenzo[b]phosphindole
• CAS: 69452-61-5
• 化学式: C₂₀H₁₇P
• 分子量: 288.329
• InChiKey: VBRYKKMBMKLDOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3,7-dimethyl-5-phenyl-5H-benzo[b]phosphindole 生成 3,7-dimethyl-5-phenyl-5H-5λ⁵-spiro[benzo[b]phosphindole-5,11'-dibenzo[b,g]phosphindole]
  参考文献：
  名称：

  Hellwinkel,D. et al., Chemische Berichte, 1979, vol. 112, p. 281 - 291

  摘要：

  DOI：
• 作为产物：
  描述：

  2-碘-1-(2-碘-4-甲基苯基)-4-甲基苯 、 苯基二氯化磷 生成 3,7-dimethyl-5-phenyl-5H-benzo[b]phosphindole
  参考文献：
  名称：

  Hellwinkel,D. et al., Chemische Berichte, 1979, vol. 112, p. 281 - 291

  摘要：

  DOI：

文献信息

• NEW POLYMER AND POLYMER LIGHT-EMITTING DEVICE USING THE SAME
  申请人：Kobayashi Satoshi

  公开号：US20080103278A1

  公开（公告）日：2008-05-01

  Provided is a polymer comprising a repeating unit represented by formula (1), wherein, A 1 represents a divalent group in which the bond distance ratio (bond distance of C(α)-A 1 /bond distance of C(α)-C(β)) is 1.10 or more; R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 , each independently represent a hydrogen atom, alkyl group, alkyloxy group, aryloxy group, arylalkyloxy group, etc. The polymer is useful as a light-emitting material, a charge transporting material, etc.

  提供的是一种聚合物，其中包含由式（1）表示的重复单元，其中A1表示具有结合距离比（C（α）-A1的结合距离/C（α）-C（β）的结合距离）为1.10或更多的二价基团；R1、R2、R3、R4、R5和R6各自独立地表示氢原子、烷基、烷氧基、芳氧基、芳基烷氧基等。该聚合物可用作发光材料、电荷传输材料等。
• New polymer and polymer light-emitting device using the same
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2067807A1

  公开（公告）日：2009-06-10

  1. A polymer having a polystyrene reduced number average molecular weight of 103-108, and comprising a repeating unit of formula (1): wherein A1 is a divalent group represented by -Z- or -Z-Z-, in which Z is an atomic group which may have a substituent; A1 represents a divalent group in which the bond distance ratio (bond distance C2-A1 bond distance C2-C1) is 1.10 or more, in which C2 is the carbon of the α-position, and C1 is the carbon of the β-position, respectively to A1; R1, R2, R3, R4, R5, and R6, each independently represent a hydrogen atom, halogen atom, alkyl group, alkenyl group, alkynyl group, alkyloxy group, alkylthio group, alkylamino group, aryl group, aryloxy group, arylthio group, arylamino group, arylalkyl group, arylalkyloxy group, arylalkylthio group, arylalkylamino group, substituted silyl group, acyl group, acyloxy group, imino group, amide group, arylalkenyl group, arylalkynyl group, monovalent heterocyclic group, or cyano group; R2 and R3 may be connected to form a ring; and R4 and R5 may be connected to form a ring, wherein A1 is a divalent group of formula (5):         -S-S-     (5)

  1.一种聚合物，其聚苯乙烯还原数平均分子量为 103-108，包含式（1）的重复单元： 其中A1是由-Z-或-Z-Z-代表的二价基团，其中Z是可具有取代基的原子团；A1代表键距比(键距C2-A1键距C2-C1)为1.10或更大，其中C2是α位的碳，C1是β位的碳，分别与A1；R1、R2、R3、R4、R5 和 R6 各自独立地代表氢原子、卤素原子、烷基、烯基、炔基、烷氧基、烷硫基、烷基氨基、芳基、芳氧基、芳硫基、芳基氨基芳烷基、芳烷氧基、芳烷硫基、芳烷氨基、取代硅烷基、酰基、酰氧基、亚氨基、酰胺基、芳烯基、芳炔基、单价杂环基或氰基；R2 和 R3 可连接形成一个环；以及 R4 和 R5 可连接形成一个环，其中 A1 是式 (5) 的二价基团： -S-S- (5)
• HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Kim Young-Kook

  公开号：US20130032787A1

  公开（公告）日：2013-02-07

  A heterocyclic compound represented by Formula 1 or Formula 2 below, and an organic light-emitting device including the heterocyclic compound. The organic light-emitting device may include an organic layer containing the heterocyclic compound, and thus may have a low driving voltage, a high-emission efficiency, and long lifespan characteristics. wherein R 1 to R 12 , Ar 1 , Ar 2 , A, B, a, and b are defined as in the specification.
• US7662478B2
  申请人：——

  公开号：US7662478B2

  公开（公告）日：2010-02-16
• US9278927B2
  申请人：——

  公开号：US9278927B2

  公开（公告）日：2016-03-08