5-(pyridin-2-ylmethoxy)isophthalic acid | 1273587-73-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(pyridin-2-ylmethoxy)isophthalic acid
• 英文别名: 5-(Pyridin-2-ylmethoxy)benzene-1,3-dicarboxylic acid
• CAS: 1273587-73-7
• 化学式: C₁₄H₁₁NO₅
• 分子量: 273.245
• InChiKey: WRNDISNPXUJDAR-UHFFFAOYSA-N

物化性质

• 沸点：
  541.3±45.0 °C(Predicted)
• 密度：
  1.420±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  96.7
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  nickel(II) chloride hexahydrate 、 5-(pyridin-2-ylmethoxy)isophthalic acid 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 72.0h， 以53%的产率得到
  参考文献：
  名称：

  Synthesis, Crystal Structures, and Properties of Three Complexes of 5-(pyridin-2-ylmethoxy) Isophthalic Acid

  摘要：

  Three new coordination compounds, namely, [(HL)(2)M(H2O)(4)] (M = Co, (1); M = Mn, (2); M = Ni, (3), H2L D 5-(pyridin-2-ylmethoxy) isophthalic acid), have been hydrothermally synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The structures of complexes 1-3 are strikingly similar and the three complexes are mononuclear compounds. In complexes 1-3, the H2L ligand is partially deprotonated. In addition, the photoluminescent behavior of 2 and the H2L ligand has been investigated in detail.

  DOI：

  10.1080/15533174.2013.867882

文献信息

• Two new metal-organic frameworks with different topological networks: syntheses, crystal structures and luminescent properties
  作者：Qifeng Liu

  DOI：10.1080/24701556.2021.1966450

  日期：——

  4)-connected sqc1387-type net topology, and compound 2 features a two-dimensional (2D) wavy layer with (3,6)-connected kgd-type net topology, which further stacked together under weak Van der Waals forces, generating a 2D→3D interdigitated supramolecular framework. The luminescent experiments revealed that these two compounds display intense blue luminescence at room temperature.

  摘要 两种新的金属有机骨架，其分子式为 [Zn(L)(4,4'-bipy) 0.5 ] n ( 1 ) 和 [Cd(L)] n ·0.5n(H 2 O) ( 2 ) (H 2 L = 5-(吡啶-2-基甲氧基)-间苯二甲酸，4,4'-bipy = 4,4'-联吡啶) 已通过水热合成并通过单晶 X 射线衍射分析进行结构表征。化合物1具有具有 (3,4) 连接的sqc1387型网络拓扑的 2 重互穿三维 (3D) 框架，化合物2具有具有 (3,6) 连接的二维 (2D) 波浪层公斤型网络拓扑结构，在弱范德华力下进一步堆叠在一起，生成 2D→3D 叉指超分子框架。发光实验表明，这两种化合物在室温下显示出强烈的蓝色发光。
• Synthesis and characterization of a novel coordination polymer with isolated tetranuclear lead(II) clusters as building subunits
  作者：Xin Zhang、Jian-Kai Cheng、Pei-Xiu Yin、Yuan-Gen Yao

  DOI：10.1016/j.molstruc.2010.10.039

  日期：2011.3

  Abstract A novel coordination polymer, [Pb4(L1)3(μ4-O)(H2O)]n (1 H2L1 = 5-(pyridine-2-ylmethoxy)-isophthalic acid), was hydrothermally synthesized, which contains μ4-oxygen-bridged Pb4O tetrahedral clusters as building subunits. These isolated Pb4O tetrahedral clusters are combined by the L1 ligands, extending into a two-dimensional (2D) layered motif. Finally, these parallel layers are further linked

  摘要 水热合成了一种新型配位聚合物[Pb4(L1)3(μ4-O)(H2O)]n (1 H2L1 = 5-(pyridine-2-ylmethoxy)-isophthalic acid)，其中含有μ4-氧-桥接 Pb4O 四面体簇作为构建亚基。这些孤立的 Pb4O 四面体簇由 L1 配体结合，延伸到二维 (2D) 分层基序中。最后，这些平行层通过分子间 CH⋯π 相互作用进一步连接，形成三维（3D）堆叠的超分子结构。此外，该聚合物在室温下表现出强烈的光致发光。
• A multi-functional Tb-organic network featuring high selectivity fluorescent sensing for Fe3+, Cr2O72−, tetracycline and 2,4,6-trinitrophenol in aqueous solution
  作者：Ting Gao、Yixia Ren、Zhixiang Wang、Meili Zhang、Jia Cao、Jijiang Wang

  DOI：10.1016/j.jssc.2022.123002

  日期：2022.5

  A novel two-dimensional Tb(III)-organic network, named as [Tb2(pyia)3 (phen)2(H2O)]·H2O(1), based on 5-(pyridine-2-ylmethoxy) isophthalic acid (H2pyia) and 1,10-phenanthroline (phen) has been synthesized hydrothermally. Structural analysis shows 1 exhibits two-dimensional network featuring the paddle-wheel binuclear secondary building units [Tb2(COO)4]2-. Fluorescent sensing properties exhibit 1 has

  一种基于5-(pyridine-2- ylmethoxy)的新型二维Tb(III)-有机网络，命名为[Tb 2 (pyia) 3 (phen) 2 (H 2 O)]·H 2 O( 1 ) ) 间苯二甲酸 (H 2 pyia) 和 1,10-菲咯啉 (phen) 已通过水热法合成。结构分析表明1展示了以桨轮双核二级建筑单元 [Tb 2 (COO) 4 ] 2-为特征的二维网络。已发现荧光传感特性1可高选择性和灵敏地检测 Fe 3+离子 (328 nM)、Cr 2O 7 2−阴离子 (526 nM)、四环素 (74.8 nM) 和 2,4,6-三硝基苯酚 (80 nM) 具有较低的 LOD 值。因此，复合物1可用作多响应发光传感器材料。
• A new luminescent Pb(II) coordination polymer based on designed pyridinecarboxylate ligand
  作者：Qifeng Liu、Wei Liu

  DOI：10.1080/15533174.2016.1212239

  日期：2017.5.4

  A new Pb(II) compound, namely Pb-2(L)(2)(H2O)(2)}(n) (1 H2L = 5-(pyridyl-4-ylmethoxy) isophthalic acid), has been synthesized by the reactions of Pb(II) ions and H2L. Single-crystal X-ray analysis reveals that compound 1 features a three-dimensional (3D) chiral framework based on 1D right-handed helical Pb-2(COO)(2)}(n) chains. Moreover, the luminescent property of 1 was also investigated in the solid state at room temperature.
• Isomeric photoluminescent lead(II) coordination polymers based on designed pyridinecarboxylate ligands
  作者：Xin Zhang、Jiankai Cheng、Feng Chen、Mingling Sun、Yuangen Yao

  DOI：10.1016/j.inoche.2010.11.032

  日期：2011.2

  The hydrothermal reaction of Pb(OAC)2 center dot 3H2O with the flexible multidentate ligand 5-(pyridin-2-ylmethoxy)-isophthalic acid (H2L1) or 5-(pyridin-4-ylmethoxy)-isophthalic acid (H2L2), respectively, afforded two new metal-organic frameworks, [Pb2L12]n (1) and [Pb2L22]n (2). The single-crystal X-ray analysis shows that 1 is a two-dimensional (20) layered structure, whereas 2 is a three-dimensional (3D) pillar-layered network. Both of them exhibit strong yellow photoluminescence upon excitation 366 nm at room temperature. (C) 2010 Elsevier B.V. All rights reserved.