3,4-Diallylthiophen | 72326-78-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 3,4-Diallylthiophen
• 英文别名: 3,4-Bis(prop-2-enyl)thiophene
• CAS: 72326-78-4
• 化学式: C₁₀H₁₂S
• 分子量: 164.271
• InChiKey: YWGRWMCRSUTMJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3,4-Diallylthiophen 、 9-硼双环[3.3.1]壬烷 、 双氧水 以50%的产率得到
  参考文献：
  名称：

  JANSSEN G. M.; MACCO A. A.; BUCK H. M.; GODEFROI E. F., REC. TRAV. CHIM. PAYS-BAS, 1979, 98, NO 7-8, 448-451

  摘要：

  DOI：
• 作为产物：
  描述：

  3-Allyl-4-Brom-thiophen 、 3-溴丙烯 、 正丁基锂 以56%的产率得到
  参考文献：
  名称：

  JANSSEN G. M.; MACCO A. A.; BUCK H. M.; GODEFROI E. F., REC. TRAV. CHIM. PAYS-BAS, 1979, 98, NO 7-8, 448-451

  摘要：

  DOI：

文献信息

• Bone anabolic compounds and methods of use
  申请人：——

  公开号：US20030119800A1

  公开（公告）日：2003-06-26

  A variety of bone anabolic compounds are useful for maintaining and/or increasing bone mass, density, and/or strength in mammals. Preferred compounds enhance bone anabolic activity while minimizing or eliminating undesirable feminizing or masculinizing effects.

  多种骨骼增生化合物对于维持和/或增加哺乳动物的骨量、密度和/或强度是有用的。优选的化合物增强骨骼增生活性，同时最小化或消除不良的女性化或男性化效果。
• Pentathienyl-Fluorene Copolymer
  申请人：Brennan J. David

  公开号：US20070210302A1

  公开（公告）日：2007-09-13

  The present invention relates to a pentathienyl-fluorene copolymer having structural units represented by formula (I): here R and R′ are each independently a substituent or H. The invention also relates to a transistor containing this copolymer. The present invention addresses a problem in the art by providing an electroactive device with exceptionally low hysteresis.

  本发明涉及一种具有结构单元的五硫杂苯-芴共聚物，其表示为公式（I）：其中R和R'各自独立地表示取代基或H。本发明还涉及一种包含该共聚物的晶体管。本发明通过提供一种具有异常低滞后的电活性装置来解决技术上的问题。
• CROSSLINKED COMPOSITION
  申请人：Daicel Corporation

  公开号：EP2559720A1

  公开（公告）日：2013-02-20

  To provide a composition (e.g., a coating composition) useful for forming an organic semiconductor having excellent conductivity, solvent resistance, heat resistance, durability, and other properties, and an organic semiconductor formed with the composition. The composition comprises an aromatic polycarbonyl compound having a carbonyl group as a reactive site, and at least one aromatic reactive component selected from an aromatic polyamine having an amino group as a reactive site, and an aromatic heterocyclic compound having a plurality of unmodified α-carbon positions, as reactive sites, each of which is adjacent to a hetero atom of a heterocycl thereof. When the aromatic reactive component is an aromatic heterocyclic compound, the aromatic polycarbonyl compound is an aromatic polyaldehyde compound. Use of the composition in which at least one component of the aromatic polycarbonyl compound and the aromatic reactive component has not less than 3 reactive sites per molecule forms an organic semiconductor having a three-dimensional crosslinked structure.

  提供一种可用于形成具有优异导电性、耐溶剂性、耐热性、耐久性和其他性能的有机半导体的组合物（例如涂层组合物），以及用该组合物形成的有机半导体。 该组合物包括具有羰基作为反应位点的芳香族聚碳化合物，以及至少一种芳香族反应性成分，该芳香族反应性成分选自具有氨基作为反应位点的芳香族多胺和具有多个未修饰的α-碳位作为反应位点的芳香族杂环化合物，其中每个反应位点都与杂环的杂原子相邻。当芳香活性组分为芳香杂环化合物时，芳香多羰基化合物为芳香多醛化合物。使用芳香族多羰基化合物和芳香族活性组分中至少一种组分每分子具有不少于 3 个活性位点的组合物，可形成具有三维交联结构的有机半导体。
• ELECTRODE FOR SOLAR CELL, MANUFACTURING METHOD THEREFOR, AND SOLAR CELL PROVIDED WITH ELECTRODE
  申请人：Nippon Chemi-Con Corporation

  公开号：EP2693559A1

  公开（公告）日：2014-02-05

  Disclosed is an electrode body for a solar cell, which is capable of being used as a component of both an organic thin-film solar cell and a dye-sensitized solar cell, and has excellent heat resistance. This electrode body for a solar cell is provided with a substrate with a conductive part at least on the surface and a conductive polymer layer located on the conductive part of the substrate, in which the conductive polymer layer includes: a polymer derived from at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes; and an anion as a dopant to the polymer generated from at least one organic non-sulfonate compound having an anion with the molecular weight of 200 or more. Additionally, the density of the conductive polymer layer is in the range of 1.15 to 1.80 g/cm3. The dense conductive polymer layer including the anion as a dopant exhibits excellent heat resistance.

  本发明公开了一种太阳能电池电极体，该电极体可用作有机薄膜太阳能电池和染料敏化太阳能电池的组件，并具有优异的耐热性。这种太阳能电池电极体具有至少表面具有导电部分的基板和位于基板导电部分上的导电聚合物层，其中导电聚合物层包括：从至少一种选自 3,4-二取代噻吩的单体中提取的聚合物；以及作为聚合物掺杂剂的阴离子，该阴离子来自至少一种具有分子量大于等于 200 的阴离子的有机非磺酸盐化合物。此外，导电聚合物层的密度在 1.15 至 1.80 g/cm3 之间。包括阴离子作为掺杂剂的致密导电聚合物层具有优异的耐热性。
• Conductive polymer of poly(thio- or seleno-)phene type
  申请人：COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES

  公开号：US10377895B2

  公开（公告）日：2019-08-13

  The present invention relates to a conductive polymer material of poly(thio- or seleno-)phene type containing at least two distinct species of counteranion, including a first species which is an anionic form of sulphuric acid, and a second species of counteranion selected from triflate, triflimidate, tosylate, mesylate, perchlorate and hexafluorophosphate. The invention also relates to a process for preparing such a material and the use thereof as conductive film. The invention also targets a substrate coated at least partly by a film of a material as defined above, a device comprising a material as defined above as conductive material, and also the use thereof in the organic electronics, organic thermoelectricity, organic photovoltaic and organic photodetector fields.

  本发明涉及一种聚(硫或硒)酚型导电聚合物材料，该材料含有至少两种不同的反阴离子，其中第一种反阴离子是硫酸的阴离子形式，第二种反阴离子选自三氟酸盐、三亚硫酸盐、甲苯磺酸盐、甲磺酸盐、高氯酸盐和六氟磷酸盐。本发明还涉及制备这种材料的工艺及其作为导电薄膜的用途。本发明还涉及一种至少部分由上述材料薄膜涂覆的基底，一种由上述材料作为导电材料的装置，以及其在有机电子、有机热电、有机光伏和有机光电探测器领域的用途。