| 195372-97-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 195372-97-5
• 化学式: C₂₂H₂₁N₃O₃Pd
• 分子量: 481.847
• InChiKey: MMEGMIQLBOQSAT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (2,2-联吡啶)二氯钯(II) 、 N-苯甲酰-N-缬氨酸 在 KOH 作用下， 以 水 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of N-benzoyl-DL-α-valinato complexes of palladium(II), platinum(II). Crystal structure of a complex with deprotonated nitrogen coordinating to the palladium(II)

  摘要：

  Reactions of MLCl2(M = Pd(II), Pt(II); L = bipy, phen) with Bzval H-2(Bzval H-2 = N-benzoyl-DL-alpha-valine) in aqueous solution at pH similar to 9 gave three complexes [Pd(bipy)(Bzval-N,O)] (1), [Pd(phen)(Bzval-N, O)]. H2O(2) and [Pt(bipy)(Bzval-N,O)]. H2O(3). All of these complexes were characterized by elemental analysis and IR spectra. The structure of 1 has been determined by X-ray diffraction analysis. In all complexes an N-benzoyl-DL-alpha-valinate dianion coordinates to the metal ion through a deprotonated amide nitrogen and a carboxylic oxygen. There is some intramolecular interaction between phenyl ring and bipy in the complex. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00153-8