[Cu(2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)(2,6-pyridinedicarboxylate)(H2O)]*H2O | 914613-58-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)(2,6-pyridinedicarboxylate)(H2O)]*H2O
• CAS: 914613-58-4
• 化学式: C₁₉H₂₁CuN₄O₇*H₂O
• 分子量: 498.96
• InChiKey: MWBAMSHMEADTQQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 2-(pyrid-3-yl)-4,4,5,5-tetramethylimidazolidine-3-oxide-1-oxyl 、 sodium dipicolinate 以 甲醇 、 水 为溶剂， 以61%的产率得到[Cu(2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)(2,6-pyridinedicarboxylate)(H2O)]*H2O
  参考文献：
  名称：

  A novel copper(II)-radical complex with ferromagnetic interaction: Synthesis, crystal structure and magnetic properties

  摘要：

  A novel copper(II)-radical complex [Cu(NITmPy)(PDA)(H2O)] center dot (H2O) (1) (NITmPy = 2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, H(2)PDA = 2,6-pyridinedicarboxylic acid) has been synthesized and structurally characterized by X-ray diffraction methods. It crystallizes in the triclinic space group P (1) over bar. The Cu(II) ion exists in a distorted square pyramid environment. The molecules of [Cu(NITmPy)(PDA)(H2O)] center dot (H2O) are connected as a two-dimensional structure by the intermolecular hydrogen bonds. Magnetic measurements show intramolecular ferromagnetic interactions between NITmPy and Cu(II) ion and intermolecular antiferromagnetic interactions in 1. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.05.044