2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide | 676228-73-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide
• 英文别名: (Cu(2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)2[dicyanamide]2(H2O)2)
• CAS: 676228-73-2
• 化学式: C₂₈H₃₆CuN₁₂O₆
• 分子量: 700.217
• InChiKey: DISLLZNVACYRDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 sodium dicyanamide 、 2-(pyrid-3-yl)-4,4,5,5-tetramethylimidazolidine-3-oxide-1-oxyl 以 甲醇 、 水 为溶剂， 生成 2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide
  参考文献：
  名称：

  A novel ferromagnetic coupling one-dimensional complex {Cu(II)(NIT3Py)2[N(CN)2]2(H2O)2}

  摘要：

  The novel ferromagnetic coupling one-dimensional complex {Cu(NIT3Py)(2)[N(CN)(2)](2)(H2O)(2)} (NIT3Py=2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was synthesized and characterized structurally and magnetically. It crystallizes in the monoclinic space group C2/c. The Cu(II) ion is in a distorted octahedral environment. The units of {Cu(NTT3Py)(2) [N(CN)(2)](2)(H2O)(2)} were connected as one-dimensional structure by the intermolecular hydrogen bonds. Magnetic measurements show that there are intramolecular ferromagnetic interactions and intermolecular antiferromagnetic interactions within the chain. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.06.002