2,9,16,23-tetrakis(2-((E)-(((E)-benzylidene)hydrazineylidene)methyl)phenoxy)phthalocyanine | 1426332-62-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 2,9,16,23-tetrakis(2-((E)-(((E)-benzylidene)hydrazineylidene)methyl)phenoxy)phthalocyanine
• CAS: 1426332-62-8
• 化学式: C₈₈H₅₈N₁₆O₄
• 分子量: 1403.53
• InChiKey: VNSUBHPUAFHSJZ-QICUYTENSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.85
• 重原子数：
  108.0
• 可旋转键数：
  20.0
• 环数：
  17.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  244.72
• 氢给体数：
  2.0
• 氢受体数：
  18.0

反应信息

• 作为产物：
  描述：

  4-(2-{(E)-[(2E)-(phenylmethylidene)hydrazono]methyl}phenoxy)phthalonitrile 在 N,N-二甲基乙醇胺 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 反应 24.0h， 生成 2,9,16,23-tetrakis(2-((E)-(((E)-benzylidene)hydrazineylidene)methyl)phenoxy)phthalocyanine 、 、 、
  参考文献：
  名称：

  Synthesis, characterization and electrical properties of peripherally tetra-aldazine substituted novel metal free phthalocyanine and its zinc(II) and nickel(II) complexes

  摘要：

  The novel phthalonitrile containing azine segment and its corresponding tetra aldazine substituted metal free- and metallo-phthalocyanines (Zn(II) and Ni(II)) were synthesized and characterized by IR, (1)H NMR, Mass, UV-Vis spectroscopy and elemental analysis and addition to these techniques for substituted phthalonitrile (13)C NMR have been used. In addition, dc and ac electrical properties of the films of these novel phthalocyanines were investigated as a function of temperature (295-523 K) and frequency (40-10(5)Hz). Activation energy values of the films of the phthalocyanines were calculated from straight portions of the Arrhenius plot (lnσ(dc)-1/T curves) as 0.70 eV, 0.93 eV and 0.91 eV for the films of metal free, nickel- and zinc-phthalocyanines, respectively. From impedance spectroscopy measurements, it is observed that bulk resistance decreases with increasing temperature indicating semiconductor property.

  DOI：

  10.1016/j.saa.2012.12.058