1-(3-Dibutylamino-propyl)-biguanid | 41740-98-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-(3-Dibutylamino-propyl)-biguanid
• 英文别名: 1-[3-(dibutylamino)propyl]biguanide；1-(Diaminomethylidene)-2-[3-(dibutylamino)propyl]guanidine
• CAS: 41740-98-1
• 化学式: C₁₃H₃₀N₆
• 分子量: 270.421
• InChiKey: ZPRFTNGLDOPRSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  19
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  106
• 氢给体数：
  3
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二聚氰胺 、 3-(二丁胺)丙胺 生成 1-(3-Dibutylamino-propyl)-biguanid
  参考文献：
  名称：

  Noel,M. et al., Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1969, vol. 268, p. 1407 - 1409

  摘要：

  DOI：

文献信息

• CURABLE-ON-DEMAND COMPOSITION COMPRISING DUAL REACTIVE SILANE FUNCTIONALITY
  申请人：Yang Yu

  公开号：US20130178553A1

  公开（公告）日：2013-07-11

  A curable composition comprises (a) at least one inorganic or organic compound comprising reactive silane functionality comprising at least one hydrosilyl moiety; (b) at least one inorganic or organic compound comprising reactive silane functionality comprising at least one hydroxysilyl moiety, the hydroxysilyl moiety optionally being generated in situ by hydrolysis of at least one hydrosilyl moiety; and (c) at least one photoactivatable composition that, upon exposure to radiation, generates at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; with the proviso that, when component (a) is an organic polymer, then component (b) is different from component (a) and is not generated in situ by hydrolysis of component (a).

  一种可治愈的组合物包括：（a）至少一种含有反应性硅烷官能团的无机或有机化合物，其中硅烷官能团包括至少一个氢硅烷基；（b）至少一种含有反应性硅烷官能团的无机或有机化合物，其中硅烷官能团包括至少一个羟基硅烷基，羟基硅烷基可以通过至少一个氢硅烷基的水解而在原位生成；以及（c）至少一种光活性组合物，当暴露于辐射下时，生成至少一种从氨基甲酸酰胺、鸟嘌呤、磷氮烷、丙氨酸磷酸酯和其组合物中选择的碱，前提是当组分（a）是有机聚合物时，组分（b）与组分（a）不同，并且不是通过组分（a）的水解在原位生成的。
• CURABLE-ON-DEMAND POLYSILOXANE COATING COMPOSITION
  申请人：Yang Yu

  公开号：US20130101841A1

  公开（公告）日：2013-04-25

  A curable composition comprises (a) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydroxysilyl moieties; (b) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydrosilyl moieties; and (c) at least one photoactivatable composition that, upon exposure to radiation, generates at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; wherein at least one of the components (a) and (b) has an average reactive silane functionality of at least three.

  可治疗组合物包括：(a)至少一种聚二甲基硅氧烷、氟代聚二甲基硅氧烷或二者的组合物，其包含具有至少两个羟基硅基的反应性硅烷官能团；(b)至少一种聚二甲基硅氧烷、氟代聚二甲基硅氧烷或二者的组合物，其包含具有至少两个氢硅基的反应性硅烷官能团；以及(c)至少一种光致活性组分，当暴露于辐射下时，会产生从氨基化合物、胍化合物、磷氮化合物、脲基磷杂环丙烷和它们的组合物中选择的至少一种碱；其中，组分(a)和/或(b)中至少有一种的平均反应性硅烷官能团为至少三个。
• CURABLE COMPOSITION COMPRISING DUAL REACTIVE SILANE FUNCTIONALITY
  申请人：Yang Yu

  公开号：US20130102728A1

  公开（公告）日：2013-04-25

  A curable composition comprises (a) at least one inorganic or organic compound comprising reactive silane functionality comprising at least one hydrosilyl moiety; (b) at least one inorganic or organic compound comprising reactive silane functionality comprising at least one hydroxysilyl moiety, the hydroxysilyl moiety optionally being generated in situ by hydrolysis of at least one hydrosilyl moiety; and (c) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; with the proviso that, when component (a) is an organic polymer, then component (b) is different from component (a) and is not generated in situ by hydrolysis of component (a).

  一种可治愈的组合物包括：（a）至少一种含有反应性硅烷官能团的无机或有机化合物，其中该反应性硅烷官能团包括至少一个氢硅烷基；（b）至少一种含有反应性硅烷官能团的无机或有机化合物，其中该反应性硅烷官能团包括至少一个羟基硅烷基，该羟基硅烷基可以通过至少一个氢硅烷基的水解而在原位生成；以及（c）选自氨基甲酸酰胺、鸟氨酸、磷氮化物、丙磺酰膦杂环戊烷和其组合物中的至少一种碱，但当组分（a）为有机聚合物时，则组分（b）与组分（a）不同且不是通过组分（a）的水解在原位生成的。
• CURABLE COMPOSITION AND CURED MATERIAL
  申请人：Kaneka Corporation

  公开号：EP2267083A1

  公开（公告）日：2010-12-29

  An object of the present invention is to provide a curable composition which is excellent in curability and storage stability without an organotin curing catalyst which is known to be toxic. In order to achieve this object, the present inventors have studied to find that a curable composition comprising: (A) an organic polymer having a silicon-containing group cross-linkable by siloxane bond formation (reactive silyl group); (B) a guanidine compound; and (C) a methyl ester group-containing compound is effective. In addition, the present inventors have found that a cured product of this curable composition has good physical properties. Thereby, the present inventors have completed the present invention.

  本发明的目的是提供一种固化组合物，该组合物不使用已知有毒的有机锡固化催化剂，而具有极佳的固化性和贮存稳定性。为了实现这一目标，本发明者经过研究发现，一种包含以下成分的可固化组合物是有效的：(A) 具有可通过硅氧烷键形成交联的含硅基团（活性硅基）的有机聚合物；(B) 一种胍类化合物；(C) 一种含甲酯基团的化合物。此外，本发明者还发现这种可固化组合物的固化产品具有良好的物理性能。因此，本发明者完成了本发明。
• ADHESIVE-BONDED STRUCTURE COMPRISING BOTH ADHESIVE COMPOSITION AND WOOD MATERIAL
  申请人：Kaneka Corporation

  公开号：EP2684690A1

  公开（公告）日：2014-01-15

  The present invention provides a bonded structure that includes a wood material and a curable composition prepared from a reactive silyl group-containing polymer and that has high strength and boiling water resistance. The reactive silyl group-containing polymer is an environmentally friendly material having less toxicity. The use of a reactive silyl group-containing organic polymer containing a (meth)acrylate polymer and a polyoxyalkylene polymer with specific structures provides a curable composition having high strength and a high modulus, leading to the formation of a bonded structure including the composition and a wood material, which is excellent in strength and boiling water resistance. Thus, the above problem can be solved.

  本发明提供了一种粘合结构，它包括木质材料和由含活性硅基聚合物制备的可固化组合物，具有高强度和耐沸水性。含活性硅基的聚合物是一种毒性较低的环保材料。使用含有具有特定结构的（甲基）丙烯酸酯聚合物和聚氧亚烷基聚合物的含反应性硅烷基有机聚合物，可获得具有高强度和高模量的可固化组合物，从而形成包括该组合物和木质材料的粘合结构，该结构具有优异的强度和耐沸水性。从而解决了上述问题。