(N[2-P(i-Pr)2-4-methylphenyl]2)Fe(II)(2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene) | 1031209-69-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N[2-P(i-Pr)2-4-methylphenyl]2)Fe(II)(2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene)
• CAS: 1031209-69-4
• 化学式: C₄₀H₅₀FeN₂P₂
• 分子量: 676.645
• InChiKey: XBTQTZKPLWDPLR-INXADACWSA-N

反应信息

• 作为反应物：
  描述：

  (N[2-P(i-Pr)2-4-methylphenyl]2)Fe(II)(2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene) 以 氘代苯 为溶剂， 以69%的产率得到[(N[2-P(i-Pr)2-4-methylphenyl][2-N=P(i-Pr)2-4-methylphenyl])Fe(II)]2
  参考文献：
  名称：

  P═N Bond Formation via Incomplete N-Atom Transfer from a Ferrous Amide Precursor

  摘要：

  Incomplete N-atom transfer from Fe to P is observed when the ferrous amide complex (PNP)Fe(dbabh) (PNP- = N[2-P(Pr-i)(2)-4-methylphenyl](2), dbabh = 2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene), prepared from salt metathesis of (PNP)FeCl and Li(dbabh), is thermolyzed at 70 degrees C over 48 h in C6D6. Several plausible reaction pathways resulting from the transformation of (PNP)Fe(dbabh) are discussed, including the possibility of an Fe(IV) nitride as an intermediate.

  DOI：

  10.1021/ic800182m
• 作为产物：
  描述：

  (N[2-P(i-Pr)2-4-methylphenyl]2)Fe(II)Cl 、 dbabhLi(OEt2) 以 not given 为溶剂， 以65%的产率得到(N[2-P(i-Pr)2-4-methylphenyl]2)Fe(II)(2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene)
  参考文献：
  名称：

  P═N Bond Formation via Incomplete N-Atom Transfer from a Ferrous Amide Precursor

  摘要：

  Incomplete N-atom transfer from Fe to P is observed when the ferrous amide complex (PNP)Fe(dbabh) (PNP- = N[2-P(Pr-i)(2)-4-methylphenyl](2), dbabh = 2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene), prepared from salt metathesis of (PNP)FeCl and Li(dbabh), is thermolyzed at 70 degrees C over 48 h in C6D6. Several plausible reaction pathways resulting from the transformation of (PNP)Fe(dbabh) are discussed, including the possibility of an Fe(IV) nitride as an intermediate.

  DOI：

  10.1021/ic800182m