Zn(H2O)(4,4'-bipyridine)(4-sulfobenzoate)2 | 1374417-42-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Zn(H2O)(4,4'-bipyridine)(4-sulfobenzoate)2
• CAS: 1374417-42-1
• 化学式: C₇H₄O₅S*C₂₀H₂₄N₄O₄Zn
• 分子量: 649.997
• InChiKey: ZMNOMWLQVQFZIK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zinc(II) chloride 、 水 、 4,4'-联吡啶 、 potassium p-carboxybenzenesulfonate 在 NaOH 作用下， 以 水 为溶剂， 生成 Zn(H2O)(4,4'-bipyridine)(4-sulfobenzoate)2
  参考文献：
  名称：

  Two New Polymers Constructed from Bisdentate Function of the 4,4′‐Bipyridine and 4‐Sulfobenzoate

  摘要：

  Two new 4-sulfobenzoate coordination polymers based on the Zn2+/Cd2+/4-sulfobenzoate/4,4'-bipyridine system, [Zn(4,4'-bipy) (H2O)(4)] (sb) (1), [Cd-2(4,4'-bipy)(4)(sb)(2)(H2O)(3)]. 3H(2)O (2) [4,4'-bipy 5 4,4'-bipyridine; sb = 4-sulfobenzoate dianion], have been prepared and characterized by IR, elemental analysis and single-crystal X-ray analysis. Their X-ray crystal structures show that the two complexes belong to a orthorhombic system, Pca2(1) space group, a = 12.1794(8) angstrom, b = 11.3422(8) angstrom, c = 14.7572(10) angstrom and a monoclinic system, C/c space group, beta = 101.161(2)degrees, a = 12.4916(16)) angstrom, b = 19.023(2) angstrom, c = 23.501(3) angstrom for 1 and 2, respectively. Both of the complexes form 1-D chains, while the arrangement of the 1-D chains are different. In contrast to monodentate 4,4'-bipy-containing complexes reported in the literature, the bisdentate function for 4,4'-bipy in 4-sulfobenzoate transition metal system has not been reported up to now. Extensive hydrogen-bonding interactions in the 2 complexes control their crystal packing and give rise to 3D extended supramolecular networks.

  DOI：

  10.1080/15533170701608940