bis(4-methoxybenzyl) (E,Z)-muconate | 461003-90-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(4-methoxybenzyl) (E,Z)-muconate
• 英文别名: di(4-methoxybenzyl) (E,Z)-muconate；bis[(4-methoxyphenyl)methyl] (2Z,4E)-hexa-2,4-dienedioate
• CAS: 461003-90-7
• 化学式: C₂₂H₂₂O₆
• 分子量: 382.413
• InChiKey: AEKKFQWNYUAHFQ-CIIODKQPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  28
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2,4-己二烯二酸,(E,Z)- 、 alkaline earth salt of/the/ methylsulfuric acid 在 potassium carbonate 作用下， 以 六甲基磷酰三胺 为溶剂， 生成 bis(4-methoxybenzyl) (E,Z)-muconate
  参考文献：
  名称：

  对二烯聚合物的立体化学的超分子控制。

  摘要：

  DOI：

  10.1002/anie.200453738

文献信息

• Stereospecific Radical Polymerization of Substituted Benzyl Muconates in the Solid State Under Topochemical Control
  作者：Akikazu Matsumoto、Toshihiro Tanaka、Kunio Oka

  DOI：10.1055/s-2005-865320

  日期：——

  We have successfully controlled the stereochemical structure of diene polymers during radical polymerization in the solid state under UV and γ-ray radiation. The polymerization of the substituted benzyl muconates occurredvia a crystal lattice controlled reaction mechanism. The polymerization is controlled by not only diisotactic and disyndiotactic, but also meso and racemo structures to afford various

  我们已经成功地控制了在紫外和γ射线辐射下固态自由基聚合过程中二烯聚合物的立体化学结构。取代的粘康酸苄酯的聚合通过晶格控制的反应机理发生。聚合不仅受二等规和间规结构的控制，而且还受内消旋结构和外消旋结构的控制，以提供各种有规立构聚合物。
• Orientational Control of Guest Molecules in an Organic Intercalation System by Host Polymer Tacticity
  作者：Shinya Oshita、Akikazu Matsumoto

  DOI：10.1002/chem.200500771

  日期：2006.3.1

  acid)s, which are synthesized by topochemical polymerization and subsequent solid-state hydrolysis, are used as the organic host materials for intercalation. We describe the reaction behavior and layered structure of intercalation compounds using stereoregular poly(muconic acid)s and n-alkylamines as host and guest, respectively. The packing structure of the guest alkylamines was determined by X-ray diffractions

  通过拓扑化学聚合和随后的固态水解合成的四种立构规整的聚粘康酸被用作插入的有机主体材料。我们描述了分别使用立构规整的聚粘康酸和正烷基胺作为主体和客体的插层化合物的反应行为和层状结构。通过X射线衍射以及IR和拉曼光谱法确定客体烷基胺的堆积结构。我们已经发现，客体分子的取向受主体聚合物的立构规整度控制，这取决于在晶体的聚合物片中形成的二维氢键网络的结构。
• First Disyndiotactic Polymer from a 1,4-Disubstituted Butadiene by Alternate Molecular Stacking in the Crystalline State
  作者：Toshihiro Tanaka、Akikazu Matsumoto

  DOI：10.1021/ja020615r

  日期：2002.8.1

  We report the first synthesis of a disyndiotactic polymer through topochemical polymerization using di(4-methoxybenzyl)muconate as the 1,3-diene dicarboxylate monomer. It provides a tritactic polymer under photoirradiation in the crystalline state, as a result of the alternate molecular stacking in a column formed in the crystals with aid of weak hydrogen bonds such as CH/pi and CH...O intermolecular interactions.
• Supramolecular Control over the Stereochemistry of Diene Polymers
  作者：Sadamu Nagahama、Toshihiro Tanaka、Akikazu Matsumoto

  DOI：10.1002/anie.200453738

  日期：2004.7.19