2-Methyl-4-propyl-1,3-dioxolane | 140861-33-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧戊环
• 英文名称: 2-Methyl-4-propyl-1,3-dioxolane
• CAS: 140861-33-2；140861-35-4
• 化学式: C₇H₁₄O₂
• 分子量: 130.187
• InChiKey: GFGKEVLETNGWFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  氯仿 、 2-Methyl-4-propyl-1,3-dioxolane 在 sodium hydroxide 、 N,N,N-三乙基-1-十六烷基溴化铵 作用下， 反应 4.0h， 生成 (2R,4R)-2-(dichloromethyl)-2-methyl-4-propyl-1,3-dioxolane 、 (2R,4S)-2-(dichloromethyl)-2-methyl-4-propyl-1,3-dioxolane
  参考文献：
  名称：

  2,4-二取代的1,3-二氧戊环与二卤卡宾的反应

  摘要：

  DOI：

  10.1007/bf00472277

文献信息

• INSECTICIDAL BIS(SUBSTITUTED PHENYL)-1-{[4-(SATURATED HETEROCYCLYL-SUBSTITUTED)PHENYLMETHYL]- (4-PIPERIDYL)}METHANE DERIVATIVES
  申请人：Lyga John W.

  公开号：US20090082203A1

  公开（公告）日：2009-03-26

  It has now been found that certain novel bis(substituted phenyl)-1 [4-(saturated heterocyclyl-substituted)phenyl-methyl](4-piperidyl)}methane derivatives have provided unexpected insecticidal activity. These compounds are represented by formula (I); where R through R 15 , m, n, s, A, B, D and W are defined herein. In addition, compositions comprising an insecticidally effective amount of at least one compound of formula (I), and optionally, an effective amount of at least one of a second compound, with at least one insecticidally compatible carrier are also disclosed; along with methods of controlling insects comprising applying said compositions to a locus where insects are present or are expected to be present.

  现在已经发现，某些新型的双（取代苯基）-1 [4-（饱和杂环取代）苯基甲基](4-哌啶基)}甲烷衍生物提供了意想不到的杀虫活性。这些化合物由式（I）表示; 其中R到R15，m，n，s，A，B，D和W在此定义。此外，本文还披露了包含式（I）中至少一种化合物的杀虫有效量和可选地至少一种第二化合物的有效量的组合物，其中至少包含一种杀虫剂兼容载体; 以及控制昆虫的方法，包括将所述组合物应用于昆虫存在或预计存在的地点。
• THIADIAZOLE COMPOUND AND USE THEREOF
  申请人：Takyo Hayato

  公开号：US20100081693A1

  公开（公告）日：2010-04-01

  A thiadiazole compound represented by the formula (I): wherein R is a hydrogen atom, an optionally substituted C1-C7 chain hydrocarbon group etc., Z is an oxygen atom or a sulfur atom, X is a —NR 2 R 3 group etc., R 2 and R 3 each independently are a hydrogen atom, a C1-C4 alkyl group, a C3-C4 alkenyl group, a C1-C4 alkoxy group, or a phenyl group, or R 2 and R 3 bind to each other at the ends thereof to form a C2-C7 alkanediyl group, has excellent controlling effect on a noxious arthropod.
• [EN] THIADIAZOLE COMPOUND AND USE THEREOF<br/>[FR] COMPOSÉ THIADIAZOLE ET UTILISATION DE CELUI-CI
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2008032858A2

  公开（公告）日：2008-03-20

  [EN] A thiadiazole compound represented by the formula (I): wherein R is a hydrogen atom, an optionally substituted C1-C7 chain hydrocarbon group etc., Z is an oxygen atom or a sulfur atom, X is a -NR²R³ group etc., R² and R³ each independently are a hydrogen atom, a C1-C4 alkyl group, a C3-C4 alkenyl group, a C1-C4 alkoxy group, or a phenyl group, or R² and R³ bind to each other at the ends thereof to form a C2-C7 alkanediyl group, has excellent controlling effect on a noxious arthropod.
  [FR] L'invention concerne un composé thiadiazole représenté par la formule (I), dans laquelle R représente un atome d'hydrogène, un groupe à chaîne hydrocarbonée C1-C7 éventuellement substitué, etc., Z représente un atome d'oxygène ou un atome de soufre, X représente un groupe -NR²R³, etc., R² et R³ représentent chacun indépendamment un atome d'hydrogène, un groupe alkyle C1-C4, un groupe alcényle C3-C4, un groupe alcoxy C1-C4, ou un groupe phényle, ou R² et R³ se lient l'un à l'autre au niveau de leurs extrémités pour former un groupe alcanediyle C2-C7. Ledit composé présente un effet de lutte efficace contre les arthropodes nocifs.
• Reaction of 2,4-disubstituted 1,3-dioxolanes with dihalocarbenes
  作者：M. S. Klyavlin、T. K. Tkachenko、L. P. Salagaeva、S. S. Zlotskii、D. L. Rakhmankulov

  DOI：10.1007/bf00472277

  日期：1991.8