tetramethylammonium manganese bromide | 51139-56-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tetramethylammonium manganese bromide
• 英文别名: tetramethylammonium tribromomanganate；dibromomanganese;tetramethylazanium;bromide
• CAS: 51139-56-1
• 化学式: Br₃Mn*C₄H₁₂N
• 分子量: 368.796
• InChiKey: CSDPLFKCFXKLRA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.86
• 重原子数：
  9.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  manganese(II) bromide 、 四甲基溴化铵 以 氢溴酸 为溶剂， 生成 tetramethylammonium manganese bromide
  参考文献：
  名称：

  Magnetic Phase Transition in (CH₃)₄NMnBr₃(TMMB)

  摘要：

  DOI：

  10.1143/jpsj.55.2369

文献信息

• Computer simulation of exciton trapping in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">Cu</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>-doped crystals of (<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">CH</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">NMnCl</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>and (<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">CH</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">NMnBr</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>: Significance of trap efficiency in one-dimensional systems
  作者：Waldo J. Rodriguez、Michael F. Herman、Gary L. McPherson

  DOI：10.1103/physrevb.39.13187

  日期：——
• Emission dynamics from doped crystals of (CH₃)₄NMnBr₃(TMMB)‐exciton trapping in a one‐dimensional lattice
  作者：Waldo J. Rodriguez、Roy A. Auerbach、Gary L. McPherson

  DOI：10.1063/1.451849

  日期：1986.12

  The red emission from (CH3)4NMnBr3 (TMMB) crystals is quenched by small concentrations of Cu2+. The emission decay curves from TMMB crystals doped with Cu2+ deviate dramatically from simple exponential form. Consistent with the linear chain structure of TMMB, the decay curves are accurately described by expressions derived to treat exciton trapping in a one-dimensional lattice. The analysis of the data indicate that the intrachain exciton migration is rapid, with a hopping frequency at room temperature of 1011 to 1012 s−1. The temperature dependence of the emission decay curves is consistent with an energy barrier to migration of 600 to 700 cm−1. Interchain migration apparently makes a negligible contribution to exciton trapping in TMMB with the interchain hopping frequency estimated to be less than 102 s−1. Within the limits of the experimental data, energy transport in TMMB is perfectly one-dimensional.
• Effect of Hydrostatic Pressure on the Low-Temperature Phase Transitions in<b><i>N</i>(<i>C</i><i>H</i>₃)₄<i><i>X</i></i><i>B</i><i>r</i>₃</b>(<i>X</i>: Mn, Ni, Cd)
  作者：Kazuo Gesi

  DOI：10.1143/jpsj.65.1297

  日期：1996.5.15

  The effect of hydrostatic pressure on the low-temperature structural phase transitions in N(CH3)(4)XBr(3) (X: Mn, Ni, Cd) has been studied. The I-II transition temperatures of N(CH3)(4)MnBr3 (140 K at atmospheric pressure), N(CH3)(4)NiBr3 (135 K), and N(CH3)(4)CdBr3 (161 K; the ferroelectric Curie temperature) increase linearly with increasing pressure with coefficients of 0.075K K/MPa, 0.092 K/MPa, and 0.086 K/MPa, respectively. As pressure increases the II-III transition temperature of N(CH3)(4)NiBr3 (97 K) decreases with a pressure coefficients of -0.07 K/MPa. The results are compared with those previously reported for N(CH3)(4)XCl(3)-type crystals (X: Mn,Cd) and discussed.