4-{2-[4-(diphenylamino)phenyl]ethynyl}-N-(2-bromoethyl)-1,8-naphthalimide | 936614-95-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-{2-[4-(diphenylamino)phenyl]ethynyl}-N-(2-bromoethyl)-1,8-naphthalimide
• CAS: 936614-95-8
• 化学式: C₃₄H₂₃BrN₂O₂
• 分子量: 571.473
• InChiKey: JNBLSBQNFWOBKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  39.0
• 可旋转键数：
  5.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  40.62
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  4-{2-[4-(diphenylamino)phenyl]ethynyl}-N-(2-bromoethyl)-1,8-naphthalimide 在 copper(l) iodide 、 sodium azide 、 N,N-二异丙基乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 18.0h， 生成
  参考文献：
  名称：

  Photovoltaic properties of new cyanine–naphthalimide dyads synthesized by ‘Click’ chemistry

  摘要：

  Two novel cyanine dyads, in which a naphthalimide unit is attached to benzoindole ring of unsymmetric trimethine cyanine, have been synthesized via 'Click' reaction and characterized by H-1 NMR, C-13 NMR, and MS-ESI. Under the illumination of AM 1.5 (75 mW cm(-2)), the power conversion efficiency of cyanine I reached 4.8% (J(sc) = 14.5 mA cm(-2), V-oc = 0.50, FF = 0.49). The results show that the two cyanine dyes are promising sensitizers for nanocrystalline dye-sensitized solar cell. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.02.034
• 作为产物：
  描述：

  4-乙炔基三苯胺 在 bis-triphenylphosphine-palladium(II) chloride 吡啶 、 copper(l) iodide 、 三溴化磷 、 三乙胺 、 三苯基膦 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 15.0h， 生成 4-{2-[4-(diphenylamino)phenyl]ethynyl}-N-(2-bromoethyl)-1,8-naphthalimide
  参考文献：
  名称：

  Photovoltaic properties of new cyanine–naphthalimide dyads synthesized by ‘Click’ chemistry

  摘要：

  Two novel cyanine dyads, in which a naphthalimide unit is attached to benzoindole ring of unsymmetric trimethine cyanine, have been synthesized via 'Click' reaction and characterized by H-1 NMR, C-13 NMR, and MS-ESI. Under the illumination of AM 1.5 (75 mW cm(-2)), the power conversion efficiency of cyanine I reached 4.8% (J(sc) = 14.5 mA cm(-2), V-oc = 0.50, FF = 0.49). The results show that the two cyanine dyes are promising sensitizers for nanocrystalline dye-sensitized solar cell. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.02.034