cis-[Pt(PPh3)2(C6H4S-2-SiPh2CH3)2] | 910110-70-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-[Pt(PPh3)2(C6H4S-2-SiPh2CH3)2]
• CAS: 910110-70-2；910222-99-0
• 化学式: C₇₄H₆₄P₂PtS₂Si₂
• 分子量: 1330.65
• InChiKey: SPPVSSIRNDJTQM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  12.27
• 重原子数：
  81.0
• 可旋转键数：
  18.0
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  cis-dichlorobis(triphenylphosphine)platinum(II) 、 [C6H4SH-2-(SiCH3Ph2)] 在 triethylamine 作用下， 以 二氯甲烷 为溶剂， 生成 cis-[Pt(PPh3)2(C6H4S-2-SiPh2CH3)2] 、 cis-[Pt(PPh3)2(C6H4S-2-SiPh2CH3)2]
  参考文献：
  名称：

  Group 10 derivatives of the silylated sterically hindered aromatic thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2]. The crystal structures of trans-[Pd(PPh3)2(SC6H4-2-SiPh3)2], z-[Pt(PPh3)2(Cl)(SC6H4-2-SiPh3)], e-[Pt(PPh3)2(Cl)(SC6H4-2-SiCH3Ph2)], cis-[Pt(PPh3)2(SC6H4-2-SiCH3Ph2)2], trans-[Pt(PPh3)2(SC6H4-2-SiCH3Ph2)2]

  摘要：

  The reactivity of the silylated sterically hindered thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2] has been examined with transition metal complexes of group 10. A series of palladium(II) and platinum(II) complexes were obtained. Analysis of these complexes by different spectroscopic techniques and single crystal X-ray diffraction studies revealed the formulations to be dependent of the stoichiometry and relative size of the metal center and thiolate. Analogous reactions with nickel complexes afforded oxidation decomposition products. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.05.018