[Ag(NO3)(PPh3)(bpy)] | 936007-79-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ag(NO3)(PPh3)(bpy)]
• 英文别名: [Ag(NO3)(PPh3)(2,2'-bipyridyl)]；silver;2-pyridin-2-ylpyridine;triphenylphosphane;nitrate
• CAS: 936007-79-3
• 化学式: C₂₈H₂₃AgN₃O₃P
• 分子量: 588.351
• InChiKey: BOAQYDMDJMVKII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.35
• 重原子数：
  36
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  88.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 silver nitrate 、 三苯基膦 以 乙腈 为溶剂， 以95%的产率得到[Ag(NO3)(PPh3)(bpy)]
  参考文献：
  名称：

  Synthesis and structural characterization of adducts of silver(I) nitrate with ER3 (E=P, As, Sb; R=Ph, cy, o-tolyl, mes) and oligodentate aromatic bases derivative of 2,2′-bipyridyl, L, AgNO3:ER3:L (1:1:1)

  摘要：

  Twenty-one adducts of the form AgNO3:ER3:L (1: 1: 1) (E = P, As, Sb; R = Ph, cy, o-tolyl, mes; L = 2,2'-bipyridyl ('bpy')-based ligand), together with AgNO3:Pcy(3):tPY (2:2:1) and AgNO3:PPh3:tPY (1:2:1) ('tpy' (2,2':6,2"-terpyridine)), have been synthesized and characterized by analytical, spectroscopic (IR, far-IR, H-1 and P-31 NMR) and single crystal X-ray diffraction studies. The resulting com plexes are predominantly of the form [(R3E)AgL]+NO3-, with trigonal EAgN2 coordination environments, the planarity of which is perturbed by the approach of the nitrate anion. The nitrate ion shows uni- or (semi-)bidentate coordination, excepting the complex AgNO3:P(o-tol)(3):doca (1: 1: 1) (dpca = bis(2-picolyl)amine) where the anion is uncoordinated, the donor dpca being a pincer-tridentate. The complex AgNO3:Pcy(3):tpy (2:2:1), also reported, is dinuclear with a bridging unidentate nitrate and a terpyridine, the latter bridging through its central ring, with the peripheral rings forming chelates to either side, whereas the complex AgNO3:PPh3:tpy (1:2:1) is ionic with a five-coordinate silver, bonded to tridentate tpy and two phosphines. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.07.017