12,14,28,30-tetramethyl-5,13,21,29-tetraphenyl-12,14,28,30-tetrahydro-13l5,29l5-tetrabenzo[g,j,s,v][1,2,4,5,13,14,16,17]octaaza[3,9,15,21]tetraphosphacyclotetracosine 5,21-dioxide 13,29-disulfide | 132990-91-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 12,14,28,30-tetramethyl-5,13,21,29-tetraphenyl-12,14,28,30-tetrahydro-13l5,29l5-tetrabenzo[g,j,s,v][1,2,4,5,13,14,16,17]octaaza[3,9,15,21]tetraphosphacyclotetracosine 5,21-dioxide 13,29-disulfide
• CAS: 132990-91-1
• 化学式: C₅₆H₅₂N₈O₂P₄S₂
• 分子量: 1057.11
• InChiKey: UHVDEYXLFQRNRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.01
• 重原子数：
  72.0
• 可旋转键数：
  4.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  96.54
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  12,14,28,30-tetramethyl-5,13,21,29-tetraphenyl-12,14,28,30-tetrahydro-13l5,29l5-tetrabenzo[g,j,s,v][1,2,4,5,13,14,16,17]octaaza[3,9,15,21]tetraphosphacyclotetracosine 5,21-dioxide 13,29-disulfide 生成
  参考文献：
  名称：

  Polyazatetraphosphorus PC and PNN macrocycles

  摘要：

  [2+2] cyclocondensation reactions involving phosphodihydrazides and bis(2-formylphenyl)phenylphosphine or the corresponding phosphine oxide lead to new 24-membered rings incorporating intracyclic P-C and P-N-N bonds. Synthesis of a macrocyclic tetraphosphonium salt is reported.

  DOI：

  10.1016/0040-4039(91)80855-z
• 作为产物：
  描述：

  bis(2-formylphenyl)phenylphosphine oxide 、 phenylthiophosphodi(methylhydrazide) 以 二氯甲烷 为溶剂， 以89%的产率得到12,14,28,30-tetramethyl-5,13,21,29-tetraphenyl-12,14,28,30-tetrahydro-13l5,29l5-tetrabenzo[g,j,s,v][1,2,4,5,13,14,16,17]octaaza[3,9,15,21]tetraphosphacyclotetracosine 5,21-dioxide 13,29-disulfide
  参考文献：
  名称：

  Polyazatetraphosphorus PC and PNN macrocycles

  摘要：

  [2+2] cyclocondensation reactions involving phosphodihydrazides and bis(2-formylphenyl)phenylphosphine or the corresponding phosphine oxide lead to new 24-membered rings incorporating intracyclic P-C and P-N-N bonds. Synthesis of a macrocyclic tetraphosphonium salt is reported.

  DOI：

  10.1016/0040-4039(91)80855-z