copper;N,N-dicyclohexylcarbamodithioate | 51120-55-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 金属杂环化合物
• 英文名称: copper;N,N-dicyclohexylcarbamodithioate
• CAS: 51120-55-9
• 化学式: C₂₆H₄₄CuN₂S₄
• 分子量: 576.459
• InChiKey: CUBOZCNNAGNVQA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.57
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  72.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 以 水 为溶剂， 以75%的产率得到copper;N,N-dicyclohexylcarbamodithioate
  参考文献：
  名称：

  Thermal and structural characterization of a series of homoleptic Cu(II) dialkyldithiocarbamate complexes: bigger is only marginally better for potential MOCVD performance

  摘要：

  A series of Cu(II) dialkyldithiocarbamate complexes, Cu(S2CNRR')(2), with R = R' = n-Bu (1); i-Bu (2); c-Hex (3); CH2Ph (4); R = n-Bu, R' = Et (5); R = n-Pr, R' = c-PrCH2 (6); R = R' = n-Pr (7); i-Pr (8); allyl (9), were prepared. The thermal properties of the complexes were investigated to determine if their potential performance in chemical vapor deposition processes was affected by the nature of the peripheral substituents of the ancillary ligands. Modest gains in volatility were noted for 2 and 7 over the most often utilized complex with R = R' = Et, while I and 8 had thermal parameters and stability comparable to this standard. Unsymmetrical substitution, such as in 5, also improved volatility, with some loss of stability for this particular compound. X-ray diffraction studies of complexes 1-6 suggested that long range Cu...S interactions in the solid-state have little bearing on the thermal properties of this class of Cu(II) complexes. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00264-x

文献信息

• Nigam, H. L.; Pandeya, Krishna, B.; Tripathi, I. P., Journal of the Indian Chemical Society, <hi>1992</hi>, vol. 69, # 8, p. 536 - 540
  作者：Nigam, H. L.、Pandeya, Krishna, B.、Tripathi, I. P.、Shukla, P. R.、Prasad, Jagdish、Srivastava, Krishna

  DOI：——

  日期：——
• US3956235A
  申请人：——

  公开号：US3956235A

  公开（公告）日：1976-05-11