4-phenoxy-N-butyl-1,8-naphthalimide | 2494-95-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 4-phenoxy-N-butyl-1,8-naphthalimide
• 英文别名: 2-butyl-6-phenoxy-benzo[de]isoquinoline-1,3-dione；2-Butyl-6-phenoxybenzo[de]isoquinoline-1,3-dione
• CAS: 2494-95-3
• 化学式: C₂₂H₁₉NO₃
• 分子量: 345.398
• InChiKey: KEQIHWSNODTVGA-UHFFFAOYSA-N

物化性质

• 沸点：
  516.5±33.0 °C(Predicted)
• 密度：
  1.242±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  46.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-硝基-1,8-萘醛酸酐 在 potassium hydroxide 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 3.5h， 生成 4-phenoxy-N-butyl-1,8-naphthalimide
  参考文献：
  名称：

  Facile synthesis, sensor activity and logic behaviour of 4-aryloxy substituted 1,8-naphthalimide

  摘要：

  A series of 4-phenoxy- and 4-alkoxy-1,8-naphthalimide fluorophores have been synthesized in high yields at room temperature applying novel facile synthesis. One of the compounds was designed as a fluorescent PET sensor according to the "fluorophore-spacer-receptor" model. The ability of this molecule to detect protons and transition metal cations with pronounced selectivity towards Fe3+ was demonstrated. Moreover the 4-phenoxy substituted 1,8-naphthalimides were highly solvent sensitive and able to detect small quantities of water. The potential of the 1,8-naphthalimide sensor to execute INHIBIT logic function at molecular level was also demonstrated. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2013.01.008