dinaphtho[2,3-d:2′,3′-d′]benzo[1,2-b:4,5-b’]dithiophene | 942578-59-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: dinaphtho[2,3-d:2′,3′-d′]benzo[1,2-b:4,5-b’]dithiophene
• 英文别名: dinaphtho[2,3-d:2',3'-d']benzo[1,2-b:4,5-b']dithiophene；dibenzodithienoacene；14,28-dithiaheptacyclo[15.11.0.03,15.04,13.06,11.018,27.020,25]octacosa-1(17),2,4,6,8,10,12,15,18,20,22,24,26-tridecaene
• CAS: 942578-59-8
• 化学式: C₂₆H₁₄S₂
• 分子量: 390.529
• InChiKey: DVTQPPQERZPCDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  28
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,2',5',2''-tetrabromo-1,1',4',1''-dibenzoterphenyl 在 仲丁基锂 、 双(苯磺酰)硫醚 作用下， 以 四氢呋喃 、 正己烷 、 环己烷 为溶剂， 反应 0.33h， 以25%的产率得到dinaphtho[2,3-d:2′,3′-d′]benzo[1,2-b:4,5-b’]dithiophene
  参考文献：
  名称：

  HETEROACENE DERIVATIVE, TETRAHALOTERPHENYL DERIVATIVE, AND THEIR PRODUCTION METHODS

  摘要：

  公开号：

  EP2067782B2

文献信息

• High-Performance Solution-Processable N-Shaped Organic Semiconducting Materials with Stabilized Crystal Phase
  作者：Chikahiko Mitsui、Toshihiro Okamoto、Masakazu Yamagishi、Junto Tsurumi、Kazumi Yoshimoto、Katsumasa Nakahara、Junshi Soeda、Yuri Hirose、Hiroyasu Sato、Akihito Yamano、Takafumi Uemura、Jun Takeya

  DOI：10.1002/adma.201400289

  日期：2014.7

  N‐shaped organic semiconductors are synthesized via four steps from a readily available starting material. Such semiconductors exhibit preferable ionization potential for p‐type operation, thermally stable crystalline phase over 200 °C, and high carrier mobility up to 16 cm2 V–1 s–1 (12.1 cm2 V–1 s–1 on average) with small threshold voltages in solution‐crystallized field‐effect transistors.

  N形有机半导体是通过一种容易获得的起始原料通过四个步骤合成的。此类半导体在p型操作，200°C以上的热稳定晶相和较高的载流子迁移率方面表现出较好的电离势，该载流子迁移率高达16 cm 2 V –1 s –1（平均为12.1 cm 2 V –1 s –1），溶液结晶场效应晶体管中的阈值电压很小。
• ORGANIC THIN FILM TRANSISTOR, ORGANIC SEMICONDUCTOR THIN FILM, AND ORGANIC SEMICONDUCTOR MATERIAL
  申请人：FUJIFILM Corporation

  公开号：US20150166560A1

  公开（公告）日：2015-06-18

  An organic thin film transistor having a semiconductor active layer containing a compound represented by the formula (1) has a high carrier mobility and a small change in the threshold voltage after repeated operation. R 1 to R 10 represent H or a substituent, provided that any two adjacent members among R 1 to R 4 and R 6 to R 9 are bonded to each other to form a substituted or unsubstituted benzene ring.

  具有半导体活性层的有机薄膜晶体管，其包含由式（1）表示的化合物，具有高载流子迁移率和重复操作后阈值电压的小变化。R1到R10表示H或取代基，只要R1到R4和R6到R9中任意两个相邻成员相互连接以形成取代或未取代的苯环即可。
• HETEROACENE DERIVATIVE, TETRAHALOTERPHENYL DERIVATIVE, AND PROCESSES FOR PRODUCING THE SAME
  申请人：Watanabe Makoto

  公开号：US20090261300A1

  公开（公告）日：2009-10-22

  There are provided a heteroacene derivative having an excellent oxidation resistance and capable of forming a semiconductor active phase by a coating process, and an oxidation-resistant organic semiconductor material using the same, as well as an organic thin film. [Means for Resolution] A heteroacene derivative represented by the formula (1) is obtained by tetrametalation of a tetrahaloterphenyl derivative with a metalation agent and subsequent treatment of the resulting compound with reaction agents: wherein the substituents R 1 to R 4 are the same or different and each represents a hydrogen atom, a fluorine atom, a chlorine atom, an aryl group having 4 to 30 carbon atoms, an alkyl group having 3 to 20 carbon atoms, or a halogenated alkyl group having 1 to 20 carbon atoms; T 1 and T 2 are the same or different and each represents sulfur, selenium, tellurium, oxygen, phosphorus, boron, or aluminum; l and m each is an integer of 0 or 1; and rings A and B are the same or different and each has a structure represented by the following formulae (A- 1 ) or (A-2).

  提供了一种具有优异氧化抗性并能够通过涂层工艺形成半导体活性相的杂环芳烃衍生物以及使用该衍生物的抗氧化有机半导体材料，以及有机薄膜。[解决方案] 通过使用金属化试剂四甲基化四卤代苯衍生物并随后用反应试剂处理所得化合物，获得了由式（1）表示的杂环芳烃衍生物：其中取代基R1至R4相同或不同，每个代表氢原子、氟原子、氯原子、具有4至30个碳原子的芳基、具有3至20个碳原子的烷基或具有1至20个碳原子的卤代烷基；T1和T2相同或不同，每个代表硫、硒、碲、氧、磷、硼或铝；l和m各自为0或1的整数；环A和环B相同或不同，每个具有以下式（A-1）或（A-2）所表示的结构。
• A CHALCOGEN-CONTAINING ORGANIC COMPOUND AND A USE THEREOF
  申请人：JNC CORPORATION

  公开号：US20160013425A1

  公开（公告）日：2016-01-14

  A compound is represented by Formula (1): wherein, each X is independently oxygen, sulfur, or selenium; m is 0 or 1; each n is independently 0 or 1; R 1 -R 3 are each independently, for example, hydrogen or alkyl having 1 to 20 carbons; wherein (i) in the case of m=0, it is excluded that all of R 1 -R 3 are hydrogen at the same time; (ii) in the case of m=0, n=0 and in the case that m is 0, one of n is 0 and the other is 1, it is excluded that “both of X are sulfur and all R 3 s are the same atoms or groups at the same time”; (iii) in the case of m=0, n=1, it is excluded that all R 3 s are the same atoms or groups at the same time, and at least one of R 3 s is hydrogen.

  化合物由式（1）表示：其中，每个X独立地为氧、硫或硒；m为0或1；每个n独立地为0或1；R1-R3各自独立地为氢或具有1至20个碳的烷基；其中（i）在m=0的情况下，排除所有R1-R3同时为氢的可能性；（ii）在m=0，n=0的情况下，或在m为0时，其中一个为0，另一个为1的情况下，排除“X均为硫且所有R3同时为相同的原子或基团”的可能性；（iii）在m=0，n=1的情况下，排除所有R3同时为相同的原子或基团的可能性，并且至少有一个R3为氢。
• CHALCOGEN-CONTAINING ORGANIC COMPOUND AND USE THEREFOR
  申请人：JNC Corporation

  公开号：EP2966077A1

  公开（公告）日：2016-01-13

  A compound is represented by Formula (1): wherein, each X is independently oxygen, sulfur, or selenium; m is 0 or 1; each n is independently 0 or 1; R1 - R3 are each independently, for example, hydrogen or alkyl having 1 to 20 carbons; wherein (i) in the case of m = 0, it is excluded that all of R1 - R3 are hydrogen at the same time; (ii) in the case of m = 0, n = 0 and in the case that m is 0, one of n is 0 and the other is 1, it is excluded that "both of X are sulfur and all R3s are the same atoms or groups at the same time"; (iii) in the case of m = 0, n = 1, it is excluded that all R3s are the same atoms or groups at the same time, and at least one of R3s is hydrogen.

  一种化合物由式 (1) 表示： 其中，每个 X 独立地为氧、硫或硒；m 为 0 或 1；每个 n 独立地为 0 或 1；R1 - R3 独立地为氢或具有 1 至 20 个碳原子的烷基； 其中 (i) 在 m = 0 的情况下，不包括所有 R1 - R3 同时为氢； (ii) 在 m = 0、n = 0 的情况下，以及在 m 为 0、n 之一为 0、另一为 1 的情况下，不包括 "X 均为硫且所有 R3 同时为相同的原子或基团"； (iii) 在 m = 0、n = 1 的情况下，不包括 "所有 R3 同时为相同的原子或基团，且至少有一个 R3 为氢"。