| 188494-13-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 188494-13-5；52554-67-3；24151-00-6
• 化学式: C₃₆H₃₀As₂I₂Pt
• 分子量: 1061.37
• InChiKey: INYACYWGYDIARW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.59
• 重原子数：
  41.0
• 可旋转键数：
  8.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氢碘酸 、 trans-[PtMeCl(AsPh₃)₂] 以 not given 为溶剂， 生成
  参考文献：
  名称：

  trans-Diiodobis(triphenylarsine-As)platinum(II)

  摘要：

  The title compound, [PtI2{AS(C6H5)(3)}(2)], is one of a few bis-AsX(3) (X is alkyl or aryl) platinum(II) complexes isolated to date. It exhibits long Pt-As and Pt-I bonds. The difference between the two independent coordination units in the unit cell is a result of packing effects.

  DOI：

  10.1107/s0108270196013844

文献信息

• Highly Efficient Solid-State Phosphorescence of Platinum Dihalide Complexes with 9-Phenyl-9-arsafluorene Ligands
  作者：Hiroaki Imoto、Susumu Tanaka、Takuji Kato、Seiji Watase、Kimihiro Matsukawa、Takashi Yumura、Kensuke Naka

  DOI：10.1021/acs.organomet.5b00944

  日期：2016.2.8

  Platinum dihalide (chloride, bromide, and iodide) complexes with 9-phenyl-9-arsafluorene, which can be safely prepared and are air stable, were synthesized. The dibromide and diiodide complexes showed highly efficient phosphorescence even at 298 K in the solid state, and their quantum yields were up to a value of 0.52. The structures of the complexes were analyzed by Xray crystallography. Time-dependent density functional calculations support our understanding of the initial electron transition processes. The rigid and bulky structure of the arsafluorene backbone effectively induced solid-state phosphorescence unlike that of a triphenylarsine analogue, which has three unbridged phenyl groups.