[Cd(N,N-(dithiodiethylenebis(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide(-H))] | 1092973-77-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cd(N,N-(dithiodiethylenebis(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide(-H))]
• CAS: 1092973-77-7
• 化学式: C₃₂H₃₂CdN₄O₄S₄
• 分子量: 777.304
• InChiKey: HMXVNWFDMSXEFU-KKSXEPMBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N-(dithiodiethylene)bis(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide 、 cadmium(II) acetate 以 甲醇 为溶剂， 生成 [Cd(N,N-(dithiodiethylenebis(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide(-H))]
  参考文献：
  名称：

  Electrochemical synthesis, structure, magnetic and tribochemical properties of metallochelates of new azomethine ligands, bis-[2-(N-tosylaminobenzylidenealkyl(aryl)]disulfides

  摘要：

  On the basis of new ligand systems, bis-azomethines of N-tosylaminobenzaldehyde and alkyl(aryl)diaminodisulfides, mono- and binuclear chelates with 4N- and 2N2S-ligand arrangement were chemically (from metal acetates) or electrochemically (from metals in the zero oxidation state) first synthesized and characterized. Mononuclear chelates have a tetrahedral structure. In binuclear copper complexes the magnetic exchange interaction of the antiferromagnetic type was observed. Bisazomethines of disulfides were used as additives to lubricant oils.

  DOI：

  10.1134/s1070363209030128

文献信息

• Electrochemical Synthesis and Characterization of Zinc(II) and Cadmium(II) Complexes of Dianionic Tetradentate Schiff Base Ligand
  作者：Laura Rodríguez、Elena Labisbal、Antonio Sousa-Pedrares、Jaime Romero、José-Arturo García Vázquez、Antonio Sousa

  DOI：10.1002/zaac.200700209

  日期：2007.9

  oxidation of anodic metal (zinc or cadmium) in acetonitrile solution of the potentially chelating Schiff base N,N-(dithiodiethylenebis(aminylydenemethylydene)bis(1,2-phenylene)ditosylamide (H2L) afforded stable complexes of empirical formula [ML]. The crystal and molecular structures of [ZnL]·CH3CN (1) and [CdL] (2) have been determined by X-ray diffraction. In both complexes the metal atom is in a distorted

  阳极金属（锌或镉）在潜在螯合席夫碱 N,N-（二硫二亚乙基双（亚氨甲基亚甲基）双（1,2-亚苯基）二甲苯磺酰胺（H2L）的乙腈溶液中的电化学氧化得到稳定的经验式 [ML] 配合物） . [ZnL]·CH3CN (1) 和 [CdL] (2) 的晶体和分子结构已通过 X 射线衍射确定。在这两种配合物中，金属原子处于扭曲的四面体环境中，席夫碱作为四齿 N4 供体. 讨论了配合物的光谱数据（IR、ES MS 和 1H NMR 光谱）并与结构信息相关。