C,N-[2-(dimethylaminomethyl)phenyl]diphenyltin(IV) diphenyldithiophosphinate | 342371-86-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: C,N-[2-(dimethylaminomethyl)phenyl]diphenyltin(IV) diphenyldithiophosphinate
• CAS: 342371-86-2
• 化学式: C₃₃H₃₂NPS₂Sn
• 分子量: 656.44
• InChiKey: IONAJROMRPQGRU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯基二硫代磷酸铵 、 C,N-[2-(dimethylaminomethyl)phenyl]diphenyltin(IV) chloride 以 二氯甲烷 为溶剂， 以92%的产率得到C,N-[2-(dimethylaminomethyl)phenyl]diphenyltin(IV) diphenyldithiophosphinate
  参考文献：
  名称：

  Hypervalent organotin(IV) derivatives containing [2-(Me2NCH2)C6H4]Sn moieties. Competition between nitrogen and chalcogen atoms for coordination to the metal centre

  摘要：

  [2-(Me2NCH2)C6H4]SnPh2Cl (1) was prepared by reacting Ph2SnCl2 with [2-(Me2NCH2)C6H4]Li in toluene. The reactions of (1) with the ammonium salt of the appropriate thiophosphinato ligand in 1:1 molar ratio afford the isolation of [2 (Me2NCH2)C6H4]SnPh2L [L= S(S)PPh2 (2), O(S)PPh2 (3)] as white crystalline solids. The molecular structure of 1-3 was determined by single-crystal X-ray diffraction. Their crystals contain monomeric units with the metal atom exhibiting a distorted trigonal bipyramidal coordination environment, The SnC3 moiety is almost planar. The N atom of the pending CH2NMe2 arm is strongly coordinated to the metal centre (Sn(1)-N(1) 2.519(2), 2.548(3), 2.481(2) Angstrom for 1, 2 and 3, respectively), trans to the Cl, O or S atoms (N(1)-Sn(1)-Cl(1) 170.49(6)degrees N(1)-Sn(1)-S(1) 169.06(8)degrees N(1)-Sn(1)-O(1) 168.58(8)degrees respectively). The S atom double bonded to phosphorus is not involved in intra- or intermolecular coordination to tin. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00871-8