1,4-bis(ferrocenyl)-2,3-diazabuta-1,3-diene | 42612-90-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,4-bis(ferrocenyl)-2,3-diazabuta-1,3-diene
• 英文别名: 1,2-diferrocenylidenehydrazine；formylferrocene azine；cyclopenta-1,3-diene;1-cyclopenta-2,4-dien-1-yl-N-(cyclopenta-2,4-dien-1-ylmethylideneamino)methanimine;iron(2+)
• CAS: 42612-90-8
• 化学式: C₂₂H₂₀Fe₂N₂
• 分子量: 424.108
• InChiKey: NFAQVWWKINJPII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  十二羰基三铁 、 1,4-bis(ferrocenyl)-2,3-diazabuta-1,3-diene 以 苯 为溶剂， 以10%的产率得到
  参考文献：
  名称：

  Synthesis of hexacarbonyldiiron complexes from azines of the aromatic series

  摘要：

  DOI：

  10.1007/bf00948261
• 作为产物：
  描述：

  二茂铁甲醛 在 一水合肼 作用下， 以 甲醇 为溶剂， 反应 15.0h， 生成 1,4-bis(ferrocenyl)-2,3-diazabuta-1,3-diene
  参考文献：
  名称：

  一种新的多才多艺的嗪配体：弹性弯曲，单晶至单晶转变和荧光开启Al（III）传感器

  摘要：

  我们报告了一种罕有的基于嗪的配体（H 3 L）的两个独特特性的组合：在固态晶体材料中，它显示出高度的柔韧性和弹性，一旦被光触发，其单相的相变将导致轻微的偏差。晶体到单晶体（SCSC）级别。此外，在溶液状态下，它可作为高度选择性，灵敏且可逆的Al 3+传感器，检测极限为42 nM。

  DOI：

  10.1039/c7cc04392a

文献信息

• Synthesis, Anti‐migration and Catalytic Effect of Ferrocene Azine Derivatives on the Thermal Decomposition of Ammonia Perchlorate
  作者：Huimin Guo、Da Huo、Haiying Zhao、Shufeng Chen

  DOI：10.1002/zaac.202200053

  日期：2022.4.26

  of these ferrocenylazines on the thermal degradation of AP were studied by DSC and TG. The results confirmed that the catalytic performance of azine without bisferrocenylpropane was inferior to that of Catocene (Cat), while the catalytic performance of azine with bisferrocenylpropane was equivalent to that of Cat. Anti-migration studies showed that both mononuclear ferroceneazines and Cat showed mobility

  二茂铁燃速催化剂（BRC）因其催化性能高而成为促进复合固体推进剂燃烧的常用催化剂，但该类催化剂存在易迁移的缺点。高氯酸铵(AP)是复合固体推进剂的主要氧化剂，其热降解行为对推进剂的燃烧有重要影响。合成了新的单核和多核二茂铁BRCs，并通过UV-Vis、NMR、HRMS和IR光谱对其结构进行了表征。通过DSC和TG研究了这些二茂铁嗪对AP热降解的催化作用。结果证实，没有二茂铁基丙烷的吖嗪的催化性能不如卡茂（Cat），而吖嗪与双二茂基丙烷的催化性能与 Cat 相当。抗迁移研究表明，单核二茂铁和 Cat 均表现出迁移性，而多核二茂铁在长期储存后不迁移。因此，多核二茂铁是一种具有应用前景的新型高效、非迁移性BRC。
• Synthesis and crystal structures of mono-, bis- as well as tris-mercurated complexes with ferrocenylazines
  作者：Xin-Qi Hao、Jun-Fang Gong、Wen-Tao Song、Yang-Jie Wu、Mao-Ping Song

  DOI：10.1016/j.inoche.2006.11.014

  日期：2007.3

  Abstract The mono-(cyclomercurated) complex (2) and bis-(cyclomercurated) complexes (3) as well as the first example of a tris-mercurated ferrocenylimine (4) have been conveniently prepared from the reaction of ferrocenylazines (1) with Hg(OAc)2 and subsequent treatment with LiCl. All the new compounds were characterized by elemental analysis, 1H NMR and IR spectra. X-ray single crystal analysis confirms

  摘要 单（环汞）配合物（2）和双（环汞）配合物（3）以及三汞二茂铁亚胺的第一个例子（4）已通过二茂铁（1）与汞的反应方便地制备。 (OAc)2 并随后用 LiCl 处理。所有新化合物均通过元素分析、1H NMR和IR光谱表征。X 射线单晶分析证实，由于分子间桥连的 Cl-Hg 键和弱分子间 N-Hg 配位，配合物 2 以四聚体形式存在于晶体中。而3b和4具有由分子间桥接的Cl-Hg键和CH(Cp)⋯Cl氢键形成的一维链结构。
• [EN] DIAZAPHOSPHACYCLES<br/>[FR] DIAZAPHOSPHACYCLES
  申请人：WISCONSIN ALUMNI RES FOUND

  公开号：WO2005042546A3

  公开（公告）日：2005-09-01
• Two novel unsymmetrical ferrocene based azines and their complexing abilities towards Cu(II): Spectroscopy, crystal structure, electrochemistry and DFT calculations
  作者：Mustafa Emirik、Kaan Karaoğlu、Kerim Serbest、Ufuk Çoruh、Ezequiel M. Vazquez Lopez

  DOI：10.1016/j.poly.2014.12.044

  日期：2015.3

  Two new ferrocenyl-substituted unsymmetric azine ligands and their Cu(II) complexes were prepared. The redox active ferrocene-based azine ligands 1 and 2 were obtained by the condensation of 1-RE)-hydrazinylidenemethyllnaphthalen-2-o1 and 2-[(E)-hydrazinylidenemethyI]-4-nitrophenol with ferrocenecarboxaldehyde, respectively. The structures of the ligands and their Cu(II) complexes were characterized by IR, UV-Vis, NMR, X-ray, magnetic measurements and TG techniques. The 2-[(E)-hydrazinylidenemethyl]-4-nitrophenol derivative azine ligand (2) was found to be rearranged by the Cu(II) ion without water or acid/base catalyst. The redox behaviors of the ferrocene derivative compounds were investigated by cyclic voltammetry. Structural parameters and spectroscopic properties of the azine ligands (1 and 2) and the Cu(II) complex (1a) were calculated using DFT and TD-DFT/CPCM methods and the results were compared with the experimental data. (C) 2015 Elsevier Ltd. All rights reserved.
• A bis(cyclopalladated) tetranuclear derivative of methyl ferrocenyl ketone azine: [{Pd[(η⁵-C₅H₅)Fe(η⁵-C₅H₃)CMeN]Cl(PPh₃)}₂]
  作者：Ramón Bosque、Concepción López、Joaquim Sales、Xavier Solans、Jack Silver

  DOI：10.1039/dt9960003195

  日期：——

  The bis(cyclopalladated) tetranuclear compound [Pd[(eta(5) -C5H5)Fe(eta(5)-C5H3)CMe=N]Cl(PPh3)}(2)] has been prepared and characterized. Proton and P-31 NMR spectra reveal the presence of four diastereomers in solution. The crystal structure of the meso form has been determined by X-ray crystallography. This confirms the existence of two five-membered palladacycles with a sigma(Pd-C-sp2,C-ferrocene) bond. Electrochemical studies, based on cyclic voltammetry, and Mossbauer spectra are also reported.