N,N'-disalicylidene-1,3-diamino-4-nitrobenzene | 1169932-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N,N'-disalicylidene-1,3-diamino-4-nitrobenzene
• 英文别名: 1,3-bis(salicylidenimino)-4-nitrobenzene
• CAS: 1169932-65-3
• 化学式: C₂₀H₁₅N₃O₄
• 分子量: 361.357
• InChiKey: PBMISMPIOLRKCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.51
• 重原子数：
  27.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  108.32
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  N,N'-disalicylidene-1,3-diamino-4-nitrobenzene 、 nickel diacetate 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 生成 catena-poly[Ni(μ-N,N'-disalicylidene-1,3-diamino-4-nitrobenzene-O,N;O',N')]
  参考文献：
  名称：

  Metal-containing polymers based on disalicylidenediamines and their electrophysical properties

  摘要：

  Metal-containing poly(disalicylidenediamines) exhibiting semiconductor properties were prepared by polycondensation of salicylidene derivatives of aromatic diamines with metal (Fe, Co, Ni, Cu) acetates. The data obtained confirm that the transfer of charge carriers in these polymers occurs along the chain through "nonclassical" polyconjugation zones formed via multiple intramolecular donor-acceptor interactions of lone electron pairs of the azomethine groups with the unoccupied d orbitals of the metal ions.

  DOI：

  10.1134/s1070427214110202
• 作为产物：
  描述：

  对硝基间苯二胺 、 水杨醛 生成 N,N'-disalicylidene-1,3-diamino-4-nitrobenzene
  参考文献：
  名称：

  Synthesis and spectral characteristics of silicon-containing poly(salicylidene azomethines) derived from aromatic di- and tetraamines

  摘要：

  New silicon-containing poly(salicylidene azomethines) were prepared by polycondensation of di-or tetrasalicylidene derivatives of aromatic di- or tetraamines. The spectral data suggest the occurrence of noncovalent transannular donor-acceptor interaction N -> Si providing "nonclassical" conjugation.

  DOI：

  10.1134/s1070427208080156