copper(II) octakis[(3,4-dimethoxyphenyl)thio]phthalocyaninate | 1448848-09-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: copper(II) octakis[(3,4-dimethoxyphenyl)thio]phthalocyaninate
• CAS: 1448848-09-6
• 化学式: C₉₆H₈₀CuN₈O₁₆S₈
• 分子量: 1921.81
• InChiKey: ARRHJJYBLOAIPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,5-bis(3,4-(dimethoxyphenylthio))phthalonitrile 、 copper diacetate 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 戊醇 为溶剂， 反应 18.0h， 以20.3%的产率得到copper(II) octakis[(3,4-dimethoxyphenyl)thio]phthalocyaninate
  参考文献：
  名称：

  Effects of peripheral and nonperipheral substitution to the spectroscopic, electrochemical and spectroelectrochemical properties of metallophthalocyanines

  摘要：

  The syntheses, spectroscopic and electrochemical properties of metallo-phthalocyanine complexes, tetra- and octa-substituted with 3,4-(dimethoxyphenylthio) moieties at non-peripheral and peripheral positions were studied. These complexes were characterized by FT-IR, mass spectroscopy, electronic spectroscopy and electrochemical methods. 3,4-(Dimethoxyphenylthio) moieties increase the solubility of the complexes in various polar and nonpolar organic solvents and prevent the aggregation (in the same solvents) within a wide concentration range. Electronic absorption spectroscopy revealed that the presence of electron donating sulphur on synthesized complexes shift the Q-band of the complexes to the higher wavelengths. Redox active metal centers, Co-II, Fe-II and (MnOAc)-O-III into the phthalocyanine core extend the redox worthy of the complexes due to the reversible metal-based reduction and oxidation couples of the metal centers. In situ electrocolorimetric measurements of the complexes allow quantification of color coordinates of each electrogenerated anionic and cationic redox species. Electrochemical and in situ spectroelectrochemical analysis indicate that cobalt and manganese phthalocyanines catalyze the molecular oxygen in aprotic media. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2013.04.166

文献信息

• Flying-seed-like liquid crystals 5: Liquid crystals based on octakisphenylthiophthalocyanine and their optical properties
  作者：Aya Ishikawa、Kazuchika Ohta、Mikio Yasutake

  DOI：10.1142/s1088424615500479

  日期：2015.5

  We have synthesized three novel flying-seed-like liquid crystals based on phthalocyaninato copper(II) (abbreviated as PcCu ) substituted by bulky groups (o- C1) PhS (i), (m- C1) PhS (j), [m, p-( C1)2] PhS (k)} instead of using long alkyl chains, in order to investigate their mesomorphism. Their phase transition behavior and the mesophase structures have been established by using a polarizing optical

  我们合成了三种新型的基于酞菁铜（II）（缩写为PcCu）被大体积基团（o- C1) PhS (i), (m- C1) PhS (j), [m, p-( C1)2] PhS (k)} 代替使用长烷基链，以研究它们的介晶。它们的相变行为和中间相结构已经通过使用偏光光学显微镜、差示扫描量热仪和温度相关的小角 X 射线衍射仪确定。结果，[(oC1)PhS]8PcCu (8i), [(mC1)PhS]8PcCu (8j) 和 [m,p-(C1)2]PhS}8PcCu (8k) 显示一个 Coltet.o中间相 314.9~362.9 °C, a Col罗(P2m) 中间相在 287.4~334.2°C 和 Col罗(P2m) 中间相分别在 331.8~386.8°C。非常有趣的是，每种衍生物因此在非常高的温度下表现出柱状中间相。介晶显然起源于新的庞大群（i~k）。还值得注意的是，与相应的含 PhO