[Cu(II)(8-quinolinylacetate)Cl] | 869064-56-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(II)(8-quinolinylacetate)Cl]
• CAS: 869064-56-2
• 化学式: C₁₁H₈NO₃*Cl*Cu
• 分子量: 301.188
• InChiKey: BAJKPOBJZJUXRL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.63
• 重原子数：
  17.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  62.25
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2-喹啉-8-氧乙酸 在 NaOH 作用下， 以 甲醇 、 水 为溶剂， 以71%的产率得到[Cu(II)(8-quinolinylacetate)Cl]
  参考文献：
  名称：

  Carboxylate-bridged helical-chain Cu(II) complex and zig-zag chain Ni(II) and Co(II) complexes from 8-quinolinyloxyacetate

  摘要：

  Tridentate carboxylate-containing ligand L (L = 8-quinolinyloxyacetate) reacts with M(II) chloride (M = Cu, Ni and Co) to give rise to three coordination polymers [CuLCl]n (1), {[NiL(H2O)(2)](ClH2O)-H-.}(n) (2), and {[CoL(H2O)(2)](ClH2O)-H-.}(n) (3), respectively. Complex 1 is a helix chain polymer while 2 and 3 are two zig-zag chain polymers. The bridging carboxylate groups are in anti-anti bridging mode in complex 1 while they are within syn-anti conformation in 2 and 3. In 1, carboxylate groups link two basal positions in basal-apical, while in complexes 2 and 3, they are basal-basal positions. The structures of these complexes have been determined by X-ray crystallography. Interestingly, three chain complexes are also linked to form 3D networks through hydrogen bonds. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.05.031