Al(OC6H2Bu(t)3-2,4,6)Cl2 * diethyl ether | 161531-83-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Al(OC6H2Bu(t)3-2,4,6)Cl2 * diethyl ether
• 英文别名: dichloro-(2,4,6-tritert-butylphenoxy)alumane;ethoxyethane
• CAS: 161531-83-5
• 化学式: C₂₂H₃₉AlCl₂O₂
• 分子量: 433.438
• InChiKey: OHMZVIJQTOLANQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Al(OC6H2Bu(t)3-2,4,6)Cl2 * diethyl ether 、 氢化钾 生成 [Al(OEt)(OC6H2Bu(t)3-2,4,6)2]2
  参考文献：
  名称：

  Synthesis and structures of sterically crowded aryloxide-substituted aluminium chloride

  摘要：

  The reaction of AlCl3 with Li(OR').Et(2)O (R' = C(6)H(2)Bu(3)(t)-2.4,6) in diethyl ether gave AI(OR')Cl-2.Et(2)0 1, a monomeric aryloxide compound of aluminium. Its reaction with 2 equivalents of potassium gave elemental aluminium and [Al(OEt)(OR')(2)](2) 2 containing a four-membered Al2O2 ring. Compound 1 crystallizes in the monoclinic space group P2(1)/c with a = 10.692(2). b = 21.825(4), c = 11.683(2) Angstrom and beta=115.49(3)degrees and compound 2 in the space group P $($) over bar$$ 1 with a = 10.227(2). b = 10.966(2), c = 18.493(4) Angstrom, alpha = 101.13(3). beta = 97.63(3) and gamma = 115.29(3)degrees.

  DOI：

  10.1039/dt9950000177
• 作为产物：
  描述：

  三氯化铝 、 乙醚 、 以 乙醚 为溶剂， 以92%的产率得到Al(OC6H2Bu(t)3-2,4,6)Cl2 * diethyl ether
  参考文献：
  名称：

  Synthesis and structures of sterically crowded aryloxide-substituted aluminium chloride

  摘要：

  The reaction of AlCl3 with Li(OR').Et(2)O (R' = C(6)H(2)Bu(3)(t)-2.4,6) in diethyl ether gave AI(OR')Cl-2.Et(2)0 1, a monomeric aryloxide compound of aluminium. Its reaction with 2 equivalents of potassium gave elemental aluminium and [Al(OEt)(OR')(2)](2) 2 containing a four-membered Al2O2 ring. Compound 1 crystallizes in the monoclinic space group P2(1)/c with a = 10.692(2). b = 21.825(4), c = 11.683(2) Angstrom and beta=115.49(3)degrees and compound 2 in the space group P $($) over bar$$ 1 with a = 10.227(2). b = 10.966(2), c = 18.493(4) Angstrom, alpha = 101.13(3). beta = 97.63(3) and gamma = 115.29(3)degrees.

  DOI：

  10.1039/dt9950000177