| 6490-64-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 6490-64-8
• 化学式: C₉H₁₅AlClN
• 分子量: 199.659
• InChiKey: GTPVHZYJQZLXJA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 三氯化铝 、 1-diethylalanylferrocene pyridine 以 氘代甲苯 为溶剂， 以80%的产率得到[(η5-C5H5)Fe(η5-C5H4)AlEt(Cl)(py)]
  参考文献：
  名称：

  Ferrocenylaluminum-pyridine adducts, lithium tetra(ferrocenyl)alanate, and the molecular structure of tri(ferrocenyl)aluminum-pyridine

  摘要：

  Aluminum compounds with up to four ferrocenyl groups (Fc) linked to aluminum were prepared and characterized in solution by NMR spectroscopy (H-1, C-13, Al-27 NMR), and in one case, tri(ferrocenyl)aluminum-pyridine Fc(3)Al-py in the solid state by X-ray structural analysis. The attempts to stabilize the unsymmetrical species R2Al-Fc and RAl(Fc)(2) (R = Me, Et) as the pyridine adducts were partially successful, although it proved difficult to suppress the formation of species containing Al-Cl functions completely. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.05.019