(AgCl(PPh3)2) | 82474-94-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (AgCl(PPh3)2)
• 英文别名: [AgCl(PPh3)2]；chlorosilver;triphenylphosphane
• CAS: 82474-94-0
• 化学式: C₃₆H₃₀AgClP₂
• 分子量: 667.903
• InChiKey: AVNLKIIWDFFLDC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.58
• 重原子数：
  40.0
• 可旋转键数：
  8.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  (AgCl(PPh3)2) 在 sodium 作用下， 以 乙醚 、 苯 为溶剂， 反应 74.0h， 生成 bis(triphenylphosphine)silver(I)gallium(III) tetraethylthiolate
  参考文献：
  名称：

  MES2黄铜矿材料的双金属单源前驱体（Ph3P）2M（µSEt）2E（SEt）2的合成与表征（M = Cu，Ag和E = In，Ga，Al）

  摘要：

  我们报告了I–III双金属配合物（Ph 3 P）2 M（µSEt）2 E（SEt）2（M = Cu，Ag和E = In，Ga，Al）的合成和表征，以及（ Ph 3 P）2 M（µ-Cl）2氯化铝2合成过程中分离出的复合物。硫醇盐络合物可用作单源前体（SSP），以制备各种I–III硫族化物半导体材料。制备该系列的一些SSP需要反应条件的微小变化。通过X射线衍射对有机金属配合物进行结构表征。比较了SSP的固态结构，基本反应性和作为黄铜矿材料前体的潜在适用性。

  DOI：

  10.1002/ejic.201700115
• 作为产物：
  描述：

  silver(I) chloride 在 三苯基膦 作用下， 以 氯仿 为溶剂， 生成 (AgCl(PPh3)2)
  参考文献：
  名称：

  A reinvestigation of some triphenylphosphinesilver halide complexes and their reaction with stannous chloride: 119mSn Mössbauer and 31P FT NMR studies

  摘要：

  DOI：

  10.1016/s0020-1693(00)87331-4

文献信息

• Synthesis and characterization of ternary AgInS2 nanocrystals by dual- and multiple-source methods
  作者：Lu Tian、Jagadese J. Vittal

  DOI：10.1039/b707960e

  日期：——

  The precursors [In(bipy)(SCO}Ph)3] and [Ag(SCO}Ph)] have been used to prepare monodispersed polyhedral shaped AgInS2 nanocrystals (NCs). The NCs were fully characterized by X-ray powder diffraction, transmission electron microscopy, selected area electron diffraction and energy dispersive X-ray analysis. The synthesis of AgInS2 NCs was further investigated by varying the dual- and multiple-source precursors and other parameters such as surfactants, surfactant ratio, temperature and time duration, to optimize the conditions to get better quality NCs. In all these reactions, a heterobimetallic thiobenzoate intermediate similar to the single-source precursor [(Ph3P)2AgIn(SCO}Ph)4] has been proposed to have formed which decompose subsequently to AgInS2 NCs.

  利用前驱体[In(bipy)(SCO}Ph)3]和[Ag(SCO}Ph)]制备了单分散多面体形状的 AgInS2 纳米晶体（NCs）。通过 X 射线粉末衍射、透射电子显微镜、选区电子衍射和能量色散 X 射线分析对这些纳米晶体进行了全面表征。通过改变双源和多源前驱体以及表面活性剂、表面活性剂比例、温度和持续时间等其他参数，进一步研究了 AgInS2 NCs 的合成，以优化条件，获得更高质量的 NCs。在所有这些反应中，都形成了与单源前体[(Ph3P)2AgIn(SCO}Ph)4]类似的硫代苯甲酸异重金属中间体，随后分解成 AgInS2 NCs。
• Chemistry of the PC^NHCP Ligand:  Silver and Ruthenium Complexes, Facial/Meridional Coordination, and Catalytic Transfer Hydrogenation
  作者：Pei Ling Chiu、Hon Man Lee

  DOI：10.1021/om049070v

  日期：2005.3.1

  Significantly, complex 3 can also be prepared directly from PCNHCP·HCl and RuCl2(PPh3)3 in the absence of base. Reactions of 3 with CO, phenylacetylene, and pyridine afford mer complexes mer,cis-RuCl2(CO)(PCNHCP) (4), mer,trans-RuCl2(CCHPh)(PCNHCP) (6), and mer,trans-[RuCl(py)2(PCNHCP)]Cl (7), respectively. The fac complex, fac,cis-[RuCl(bipy)(PCNHCP)]Cl (8), was produced in reaction of either 3 or

  PC NHC P的银络合物被鉴定为[Ag 3（μ-Cl）（PC NHC P）2 ] Cl 2（1）。1与AgNO 3的阴离子交换得到白色化合物，该化合物结晶为两种形式，即[Ag 3（μ-Cl）（PC NHC P）] 2（NO 3）2（2a）和[Ag 3（Cl）（NO 3）（0.5DMF）（PC NHC P）2 ] NO 3（2b），来自不同的溶剂组合。它们的结构确定揭示了令人感兴趣的结构特征，包括两者中的短的Ag··Ag相互作用。不像钌的共制剂（II）NHC络合物在文献之间的新的银卡宾转移反应1和的RuCl 2（PPH）3产生FAC - [孺2（μ-Cl）的3（PC NHC P）2 ]氯（3），产量高。卡宾转移反应的非氧化还原性质与早期报道不同，表明通过卡宾银转移制备二价钌NHC络合物是可行的合成途径。重要的是，在不存在碱的情况下，复合物3也可以直接由PC NHC P·HCl和RuCl 2（PPh
• Crystal and Molecular Structure of Palladium(II) and Silver(I) Complexes with Oxotetrazolinate Ligands [1-Me-N4C(O)]^-
  作者：Heinrich Noth、Klaus Burger、Wolfgang Beck

  DOI：10.1515/znb-2011-0917

  日期：2011.9.1

  The structures of (n-Bu3P)2Pd[1-Me-N4C(O)]2 (1) and of (Ph3P)3Ag[1-Me-N4C(O)] ・ 1-Me-4-H-N4C(O) (2) were determined by X-ray crystallography. The oxotetrazolinate ligands are N4-coordinated in contrast to the corresponding Scoordinated tetrazole-thionates. Graphical Abstract Crystal and Molecular Structure of Palladium(II) and Silver(I) Complexes with Oxotetrazolinate Ligands [1-Me-N4C(O)]-

  (n-Bu3P)2Pd[1-Me-N4C(O)]2 (1) 和 (Ph3P)3Ag[1-Me-N4C(O)] · 1-Me-4-H-N4C( O) (2) 由 X 射线晶体学测定。与相应的配位四唑-亚硫酸盐相比，氧代四唑啉配体是 N4 配位的。钯 (II) 和银 (I) 配合物与氧代四唑啉配体的图形抽象晶体和分子结构 [1-Me-N4C(O)]-
• Synthesis and structure of [(Ph3P)2Ag(μ-Cl)(μ-SC{O}Ph)In(SC{O}Ph)2]
  作者：Theivanayagam C. Deivaraj、Jagadese J. Vittal

  DOI：10.1016/s0020-1693(02)00908-8

  日期：2002.7

  The synthesis and structure of the hetero-bimetallic compound [(Ph3P)(2)Ag(mu-Cl)(mu-SCO}Ph-S)In(SCO}Ph)(2)] have been reported. The compound was synthesized by reacting [(Ph3P)(2)AgCl], InCl3.4H(2)O and NaSCO}Ph in the ratio 1:1:3 in a mixture of solvents. The structure of the compound has been determined by X-ray crystallography, The compound contains a nonplanar AgClSIn core. (C) 2002 Elsevier Science B.V. All rights reserved.
• A Pentanuclear Mixed Gold(III)−Silver(I) Phosphide with an Unusual T-Frame μ₃-Cl Bridge
  作者：M. Carmen Blanco、Eduardo J. Fernández、M. Elena Olmos、Olga Crespo、Antonio Laguna、Peter G. Jones

  DOI：10.1021/om020142x

  日期：2002.6.1

  The reaction of the mixed gold(III)-silver(I) diphenylphosphide complex [Au(C6F5)(2)(mu-PPh2)(2)Ag](2) (1) with an equimolecular amount of [AgCl(PPh3)(2)] leads to the formal insertion of the latter into 1, affording the pentanuclear derivative [Au(C6F5)(2)(mu-PPh2)AgPPh3}(mu-PPh2)}(2)(mu-Ag)(mu(3)-Cl)] (2). Surprisingly, complex 2 is also obtained by treatment of [Au(C6F5)(2)(PPh2H)(2)]ClO4 with [Ag(TfO)(PPh3)] (TfO = trifluoromethanesulfonate) and AgTfO (2:2:1) in the presence of PPN(acac) (PPN = [N(PPh3)(2)](+), acac = acetylacetonate) and PPNCl. The crystal structure of 2 has been determined by X-ray diffraction studies, and it displays an unusual, perfectly planar T-frame mu(3)-Cl atom acting as a bridge between the three silver atoms.