piperidino-thiophosphonic acid O,O'-diphenyl ester | 38945-84-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: piperidino-thiophosphonic acid O,O'-diphenyl ester
• 英文别名: Piperidino-thiophosphonsaeure-O,O'-diphenylester；Diphenoxy-piperidin-1-yl-sulfanylidene-lambda5-phosphane；diphenoxy-piperidin-1-yl-sulfanylidene-λ5-phosphane
• CAS: 38945-84-5
• 化学式: C₁₇H₂₀NO₂PS
• 分子量: 333.391
• InChiKey: LLSFUXZIVIZAEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  53.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苯氧基亚磷酰二氯 以 1,4-二氧六环 、 正己烷 为溶剂， 反应 976.0h， 生成 piperidino-thiophosphonic acid O,O'-diphenyl ester
  参考文献：
  名称：

  Dismutation of Diamidoarylphosphites

  摘要：

  Some examples of spontaneous dismutation of diamidoarylphosphites in different solvents were studied, and features of the process were revealed.

  DOI：

  10.1080/714040960

文献信息

• Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use
  作者：E. N. Rasadkina、P. V. Slitikov、E. E. Nifant’ev

  DOI：10.1134/s1070363206020046

  日期：2006.2

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.
• Borke; Kirch, Journal of the American Pharmaceutical Association (1912), 1958, vol. 47, p. 461,462
  作者：Borke、Kirch

  DOI：——

  日期：——
• Dismutation of Diamidoarylphosphites
  作者：Edward E. Nifantyev、Elena N. Rasadkina、Pavel V. Slitikov、Larisa K. Vasyanina

  DOI：10.1080/714040960

  日期：2003.11.1

  Some examples of spontaneous dismutation of diamidoarylphosphites in different solvents were studied, and features of the process were revealed.