Hg(SCN)2(2-(diphenylphosphinomethyl)pyridine)2 | 1357461-83-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Hg(SCN)2(2-(diphenylphosphinomethyl)pyridine)2
• CAS: 1357461-83-6
• 化学式: C₃₈H₃₂HgN₄P₂S₂
• 分子量: 871.368
• InChiKey: DXZNVJMCANSBTF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.46
• 重原子数：
  47.0
• 可旋转键数：
  12.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  73.36
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  mercury(II) thiocyanate 、 二苯基(吡啶-2-基甲基)膦 以 四氢呋喃 为溶剂， 以78%的产率得到Hg(SCN)2(2-(diphenylphosphinomethyl)pyridine)2
  参考文献：
  名称：

  Syntheses and coordination studies of 2-(diphenylphosphinomethyl)pyridine and its oxide towards mercury(II)

  摘要：

  Several coordination complexes of mercury(II) have been synthesized by the reaction of mercury(II) salts with 2-(diphenylphosphinomethyl)pyridine (L1) and its corresponding oxide (12). The synthesized complexes were fully characterized by elemental analysis and multinuclear NMR spectroscopy techniques. The crystal structures were determined by single-crystal X-ray crystallography. Different geometries were observed around the metal center, including distorted trigonal-pyramidal (1,3), distorted tetrahedral (2) and distorted octahedral (4,5), with the degree of distortion depending on the steric effects and the chelating capability of 2-(diphenylphosphinomethyl)pyridine and its oxide. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.01.001