A wide range of new classes of early transitionmetal and actinide compounds have been isolated with the new amido and phosphido ligands −E(CH2CH2E′R2)2 (where R = alkyl; E = N, E′ = N, P, As and E = P, E′ = P). Structural and chemical properties of metal derivatives are seen to be sensitive to variations in the ligands. Dependent on the nature of the donors, monomeric complexes with pendant bases
使用新的酰胺和磷配体−E(CH2CH2E'R2)2(其中R =烷基; E = N,E'= N,P,As和E = P,E'= P)。金属衍生物的结构和化学性质被认为对配体的变化敏感。取决于供体的性质,可以获得具有侧基的单体配合物。这些可用作制备均双金属和异双金属化合物的前体。
Duckworth, M. W.; Fowles, G. W. A.; Williams, R. G., Chemistry and industry
作者:Duckworth, M. W.、Fowles, G. W. A.、Williams, R. G.
DOI:——
日期:——
Fowles, G. W. A.; Pleass, C. M., Journal of the Chemical Society