zinc mercury tetrakis(thiocyanate) | 14481-23-3

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: zinc mercury tetrakis(thiocyanate)
• 英文别名: zinc mercury thiocyanate；thiocyanic acid ; mercury (II)-zinc-thiocyanate；Thiocyansaeure; Quecksilber(II)-zink-thiocyanat；zinc;thiocyanatomercury(1+)
• CAS: 14481-23-3
• 化学式: 4CNS*Hg*Zn
• 分子量: 498.315
• InChiKey: ALJAFAJSCHRVFT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.01
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.79
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  mercury(II) thiocyanate 、 Thiocyanic acid, zinc salt, dihydrate 以 水 为溶剂， 生成 zinc mercury tetrakis(thiocyanate)
  参考文献：
  名称：

  Spectroscopic and thermal behavior of ZnHg(SCN)4

  摘要：

  The synthesis and purification of zinc mercury thiocyanate, ZnHg(SCN)(4) (ZMTC), are described. The identity of the synthesized compound was characterized by elemental analysis, X-ray powder diffraction, infrared, Raman, and UV/Vis/NIR transmission spectra. The thermal stability and thermal decomposition of ZMTC crystal were investigated by means of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) measurements. The intermediates and final products of the thermal decomposition were identified by X-ray powder diffraction (XRPD). (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0025-5408(02)00859-0

文献信息

• Study of optimum growth condition and characterization of zinc mercury thiocyanate (ZMTC) single crystals in silica gel
  作者：P. Nisha Santha Kumari、S. Kalainathan、N. Arunai Nambi Raj

  DOI：10.1016/j.materresbull.2007.01.018

  日期：2007.12

  Abstract Some bimetallic thiocyanate complexes exhibit excellent nonlinear optical properties. Single crystals of one such material, zinc mercury thiocyanate ZnHg(SCN) 4 have been grown in silica gel with gel technique by the process of diffusions and the optimum growth condition has been studied. Crystals of 4 mm length have been obtained. Their structural, optical and thermal properties have been

  摘要 一些双金属硫氰酸盐配合物表现出优异的非线性光学特性。一种这样的材料，硫氰酸锌汞锌(SCN) 4 的单晶已经通过凝胶技术通过扩散过程在硅胶中生长，并研究了最佳生长条件。已获得4毫米长的晶体。已经研究了它们的结构、光学和热特性。使用X射线衍射仪进行结构分析，确认晶体结构为四方晶系。获得傅里叶变换红外光谱以确认官能团。已在溶液状态下记录透射光谱并确定截止波长。已通过热重分析和差热分析研究了生长晶体的热稳定性。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Hg: MVol.B3, 6.16, page 1249 - 1262
  作者：

  DOI：——

  日期：——
• Czakis, M., Studia Societatis Scientiarum Torunensis, Sectio B: (Chemia), 1960, vol. 2, # 5, p. 1 - 80
  作者：Czakis, M.

  DOI：——

  日期：——
• Czakis, M., Roczniki Chemii, 1959, vol. 33, p. 3 - 14
  作者：Czakis, M.

  DOI：——

  日期：——
• Czakis-Sulikowska, M.; Swinarski, A., Roczniki Chemii, 1962, vol. 36, p. 389 - 401
  作者：Czakis-Sulikowska, M.、Swinarski, A.

  DOI：——

  日期：——