6-(dimethylamino)-7,9-dimethylpurinium perchlorate | 37013-77-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并嘧啶类
• 英文名称: 6-(dimethylamino)-7,9-dimethylpurinium perchlorate
• 英文别名: 6-Dimethylamino-7,9-dimethyl-purinium-perchlorat；6-Dimethylamino-7,9-dimethylpurinium Perchlorat；6-(Dimethylamino)-7,9-dimethylpurinium
• CAS: 37013-77-7
• 化学式: C₉H₁₄N₅*ClO₄
• 分子量: 291.694
• InChiKey: APGLRUINFKAJQM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sodium iodide 、 6-(dimethylamino)-7,9-dimethylpurinium perchlorate 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 在 NaH 作用下， 以 乙醇 为溶剂， 以95%的产率得到iodo(η4-1,5-cyclooctadiene)(6-(dimethylamino)-7,9-dimethylpurin-8-ylidene)rhodium(I)
  参考文献：
  名称：

  N-Heterocyclic Carbenes:  Synthesis, Structures, and Electronic Ligand Properties^,

  摘要：

  N-Heterocyclic carbene (NHC) rhodium(l) complexes of general formula Rh(COD)X(NHC) are synthesized and structurally characterized (spectroscopy, X-ray diffraction). The relative sigma-donor/pi-acceptor quality of various NHC ligands was examined and classified by means of IR spectroscopy at the corresponding Rh(CO)(2)I(NHC) complexes. The first single-crystal X-ray diffraction studies of rhodium pyrazolin- and tetrazolinylidene complexes are reported. A wide variety of different azolium salts was applied to obtain rhodium and iridium complexes with two and four carbene ligands.

  DOI：

  10.1021/om0600801