RuI(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2 | 339525-96-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: RuI(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2
• CAS: 339525-96-1
• 化学式: C₄₉H₃₉IN₂P₂RuS
• 分子量: 977.85
• InChiKey: LBUJDSOFLDNIQS-MLOVYWAESA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  RuCl(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2 、 sodium iodide 在 AgNO₃ 作用下， 以 乙醇 、 二氯甲烷 、 水 为溶剂， 以92%的产率得到RuI(CS)(η(2)-C,N-C6H4N=NPh)(PPh3)2
  参考文献：
  名称：

  A novel cis-push–pull effect in cycloruthenated azobenzene thiocarbonyl-containing complexes: crystal and molecular structures of [RuX(CS)(η2-C,N-C6H4NNPh)(PPh3)2](X=Cl, I)

  摘要：

  Treatment of [RuHCl(CS)(PPh3)(3)] with Hg(o-C6H4N=NC6H5)(2) affords [RuCl(CS)(eta C-2,N-o -C6H4N=NC6H5)(PPh3)(2)] (1) in good yield, where the cyclometallated azobenzene ligand coordinates through an ortho-C and one azo-N to give a five-membered chelate ring. Reaction of 1 with AgNO3 followed by NaBr or NaI affords the chloride-exchanged products [RuX(CO)(eta C-2,N-o-C6H4N=NC6H5)(PPh3)(2)] (2, 3), whereas reaction of 1 with AgOC(O)Me or NaS2CNEt2. 2H(2)O gives the halide mono-phosphine-substituted complexes [Ru(CS)(LL)(eta C-2,N-o-C6H4NNC6H5)(PPh3)] (4, 5). In the solid-state structures of 1 and 3 there are significant changes in the bond lengths for the cyclometallated azobenzene ligand are observed relative to free azobenzene. These are discussed, with the aid of spectroscopic and crystallographic data, in terms of a cis-push-pull effect. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00692-6