[(μ-cyano)(1,4,8,11,15,18,22,25-octa-n-heptylphthalocyaninato)cobalt(III)]n | 165285-44-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: [(μ-cyano)(1,4,8,11,15,18,22,25-octa-n-heptylphthalocyaninato)cobalt(III)]n
• 英文别名: cobalt(3+);5,8,14,17,23,26,32,35-octaheptyl-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene;cyanide
• CAS: 165285-44-9
• 化学式: CN*C₈₈H₁₂₈N₈*Co
• 分子量: 1383.05
• InChiKey: AWFUQPUVYPXPNF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  26.32
• 重原子数：
  99.0
• 可旋转键数：
  48.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  129.33
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  sodium dicyano(1,4,8,11,15,18,22,25-octa-n-heptylphthalocyaninato)cobalt(III) 在 H₂O 作用下， 以 水 为溶剂， 以0%的产率得到[(μ-cyano)(1,4,8,11,15,18,22,25-octa-n-heptylphthalocyaninato)cobalt(III)]n
  参考文献：
  名称：

  Reaction of Cyanogen with Cobalt Phthalocyanines

  摘要：

  The soluble (phthalocyaninato)- and (2,3-naphthalocyaninato)cobalt(II) complexes (t-Bu)(4)PcCo, 2,3,9,10,16,17,23,24-(C7H15)(8)PcCo, 1,4,8,11,15,18,22,25-(C7H15)(8)PcCo, and (t-Bu)(4)2,3-NcCo react with cyanogen with formation of cyano-bridged oligomers of the type ([MacCo(CN)](n)). The same products are also prepared via an earlier developed method by reaction of the (phthalocyaninato)cobalt(II) compounds with KCN via K[MacCo(CN)(2)] complexes and treatment with water. The conductivities of the obtained cyano-bridged systems ([MacCo(CN)](n)) are measured, and [(t-Bu)(4)-2,3-NcCo(CN)](n) shows a remarkable conductivity of 8 x 10(-2) S/cm.

  DOI：

  10.1021/ic00118a009