(4-叔丁基苯基)氰酸酯 | 1132-16-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: (4-叔丁基苯基)氰酸酯
• 英文名称: p-tert-Butyl-phenylcyanat
• 英文别名: 4-tert.-Butyl-phenylcyanat；4-tert-Butylphenyl cyanate；(4-tert-butylphenyl) cyanate
• CAS: 1132-16-7
• 化学式: C₁₁H₁₃NO
• 分子量: 175.23
• InChiKey: RTFKTGCPZFNXDW-UHFFFAOYSA-N

物化性质

• 沸点：
  80 °C(Press: 0.5 Torr)
• 密度：
  1.009±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  33
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2929909090

反应信息

• 作为反应物：
  描述：

  (4-叔丁基苯基)氰酸酯 反应 48.0h， 生成 2,4,6-tris-(4-tert-butyl-phenoxy)-[1,3,5]triazine
  参考文献：
  名称：

  尝试合成受阻的2,4,6-三芳氧基-s-三嗪：碳酸双（2,4-二叔丁基苯基）酯-晶体结构

  摘要：

  一些较少位阻2,4,6-三-芳氧基-小号-triazines分别通过相应的酚的反应如用溴化氰（的BrCN）的起始材料，以获得相应的arylcyanates合成，然后三聚。出乎意料的是，2,4-二-叔-丁基-1- cyanatobenzene从2,4-二-衍生的叔丁基苯酚没有三聚但是，的确，得到双（2,4-二-叔丁基苯基）碳酸酯。2,4,6-三-芳氧基的结构小号-triazines和双（2,4-二-叔丁基苯基）碳酸酯进行了表征通过IR，手段1 H，和13个C NMR波谱。还通过X射线晶体学研究了后者的结构。

  DOI：

  10.1002/jccs.201700335
• 作为产物：
  描述：

  4-叔丁基苯酚 、 氯化氰 在 三乙胺 作用下， 生成 (4-叔丁基苯基)氰酸酯
  参考文献：
  名称：

  Grigat,E.; Puetter,R., Chemische Berichte, 1964, vol. 97, p. 3012 - 3017

  摘要：

  DOI：

文献信息

• Photocurable adhesive
  申请人：DENSO CORPORATION

  公开号：US10344191B2

  公开（公告）日：2019-07-09

  Provided is a photocurable adhesive with which curing by direct irradiation of laser light is possible with almost no occurrence of surface carbonization and which is capable of satisfactory curing even when the coating thickness is increased. A photocurable adhesive, which is cured by irradiation of laser light, is provided. The curable adhesive contains an epoxy adhesive component, a light-absorbing component for thermal curing of the epoxy adhesive component by absorption of laser light, and an inorganic filler. The content of the light-absorbing component is 0.1 mass % or less. The pre-curing thermal conductivity of the photocurable adhesive is at least 0.2 W/m·K and the post-curing thermal conductivity is at least 0.5 W/m·K.

  本发明提供了一种光固化粘合剂，可通过激光直接照射进行固化，几乎不会出现表面碳化现象，即使增加涂层厚度也能达到令人满意的固化效果。本文提供了一种通过激光照射固化的光固化粘合剂。这种可固化粘合剂包含环氧树脂粘合剂成分、通过吸收激光使环氧树脂粘合剂成分热固化的光吸收成分和无机填料。光吸收成分的含量不超过 0.1 质量%。光固化粘合剂的固化前热导率至少为 0.2 W/m-K，固化后热导率至少为 0.5 W/m-K。
• Jaeger,G.; Wenzelburger,J., Justus Liebigs Annalen der Chemie, 1976, p. 1689 - 1712
  作者：Jaeger,G.、Wenzelburger,J.

  DOI：——

  日期：——
• AROMATIC CYANATE ESTER SILANE COUPLING AGENTS
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0830410B1

  公开（公告）日：1999-04-07
• ONE LIQUID TYPE CYANATE-EPOXY COMPOSITE RESIN COMPOSITION
  申请人：Ogawa Ryo

  公开号：US20100204410A1

  公开（公告）日：2010-08-12

  The present invention is one liquid type cyanate-epoxy composite resin composition comprised of cyanate ester resin (A), epoxy resin (B), and potential curing agent (C), characterized in that the above potential curing agent is the potential curing agent containing phenol resin (b) as well as modified amine (a) which has one or more amino groups having an active hydrogen within a molecule obtained by reacting polyamine compound (a-1) with epoxy compound (a-2). The one liquid type cyanate-epoxy composite resin composition having storage stability, curing properties and high heat resistance properties at the same time can be realized by this composition.
• ONE LIQUID TYPE CYANATE-EPOXY COMPOSITE RESIN COMPOSITION, ITS HARDENED MATERIAL, MANUFACTURING METHOD THEREOF, AND MATERIALS FOR SEALING AND ADHESIVE AGENTS USING THE SAME
  申请人：Ogawa Ryo

  公开号：US20100210793A1

  公开（公告）日：2010-08-19

  The present invention is a cyanate-epoxy composite resin composition comprised of a cyanate ester resin (A), an epoxy resin (B), and a latent curing agent (C), characterized in that the latent curing agent (C) is composed of a modified polyamine (c1), a phenol resin (c2) and one or more kind of polycarboxylic acid (c3). The above modified polyamine (c1) is a modified polyamine, which is obtained by the reaction of polyamine compound (c1-1) with epoxy compound (c1-2), containing one or more amino group having an active hydrogen within a molecule.