Bicyclo[2.2.1]hept-2-ene, 5,5,6-trifluoro-6-(heptafluoropropoxy)- | 154717-36-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: Bicyclo[2.2.1]hept-2-ene, 5,5,6-trifluoro-6-(heptafluoropropoxy)-
• 英文别名: 5,5,6-trifluoro-6-(1,1,2,2,3,3,3-heptafluoropropoxy)bicyclo[2.2.1]hept-2-ene
• CAS: 154717-36-9
• 化学式: C₁₀H₆F₁₀O
• 分子量: 332.14
• InChiKey: JZEKVGIWHZEUSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  11

文献信息

• Thermoplastic norbornene resin based optical film
  申请人：——

  公开号：US20040242823A1

  公开（公告）日：2004-12-02

  An optical film is provided, which displays a positive wavelength dependency across the entire wavelength region from 400 to 800 nm, and is capable of imparting a specified retardation to transmitted light with a single sheet of film. The optical film particularly, includes a thermoplastic norbornene-based resin with a specified structure formed of a structural unit (I) which imparts a positive birefringence and a structural unit (II) which imparts a negative birefringence, and which satisfies particular conditions with respect to &Dgr;N I (&lgr;), &Dgr;N II (&lgr;), &Dgr;N I (800) and &Dgr;N II (800) wherein &Dgr;N I (&lgr;) and &Dgr;N II (&lgr;) represent the difference between a refractive index Nx(&lgr;) in an x axis direction at a wavelength &lgr;, and a refractive index Ny(s) in a y axis direction, and &Dgr;N I (800) and &Dgr;N II (800) represent the difference in refractive indexes at a wavelength of 800 nm, and the x axis represents the stretching direction and the y axis represents the in-plane direction perpendicular to the x direction.

  提供了一种光学薄膜，其在整个波长范围从400到800纳米内显示正波长依赖性，并能够通过单张薄膜赋予传输光以指定的延迟。该光学薄膜特别包括一种热塑性诺本烯基树脂，其具有特定的结构，由赋予正双折射的结构单元（I）和赋予负双折射的结构单元（II）组成，并满足与&Dgr;NI(&lgr;)、&Dgr;NII(&lgr;)、&Dgr;NI(800)和&Dgr;NII(800)相关的特定条件，其中&Dgr;NI(&lgr;)和&Dgr;NII(&lgr;)表示在波长&lgr;处x轴方向上的折射率Nx(&lgr;)与y轴方向上的折射率Ny(s)之间的差异，而&Dgr;NI(800)和&Dgr;NII(800)表示在波长为800纳米时的折射率差异，其中x轴代表拉伸方向，y轴代表垂直于x方向的平面方向。
• OPTICAL FILM, POLARIZATION PLATE AND LIQUID CRYSTAL DISPALY
  申请人：Sekiguchi Masayuki

  公开号：US20090231518A1

  公开（公告）日：2009-09-17

  [Problems] To provide an optical film for a liquid crystal display, in which a wide range of a retardation of transmitted light can be controlled in manufacturing and good viewing angle compensation effects on such as preventing light leakage or color dropout (coloring) in true black display and achieving a high contrast in all directions can be obtained when used in liquid crystal display. [Means for Solving Problems] The optical film of the invention includes a film (a) layer made of a cyclic olefin resin and a film (b) layer made of a polyimide resin or a polyetherimide resin, wherein following formulae (1) and (2) are preferably satisfied: (1) 200 nm≦Rth≦1,000 nm and (2) 0≦R550≦200 nm, wherein Rth and R550 represent the retardation in the direction of film thickness and the in-plane retardation of the film, respectively, at wavelength of 550 nm.

  [问题] 提供一种适用于液晶显示器的光学膜，可以在制造过程中控制传输光的广泛延迟范围，并在真正的黑色显示中实现良好的视角补偿效果，例如防止光泄漏或颜色丢失（着色），并在所有方向上实现高对比度。 [解决问题的方法] 本发明的光学膜包括由环烯烃树脂制成的膜（a）层和由聚酰亚胺树脂或聚醚酰亚胺树脂制成的膜（b）层，其中以下公式（1）和（2）最好满足：（1）200 nm≦Rth≦1,000 nm和（2）0≦R550≦200 nm，其中Rth和R550分别表示在550 nm波长下膜的厚度方向延迟和面内延迟。
• NORBORNENE DERIVATIVE AND NORBORNENE POLYMER OBTAINED THEREFROM THROUGH RING-OPENING POLYMERIZATION
  申请人：JSR Corporation

  公开号：EP1435350A1

  公开（公告）日：2004-07-07

  A novel norbornene derivative represented by a general formula (1m) shown below is provided. By conducting a ring opening polymerization of this norbornene derivative, or by performing a subsequent hydrogenation following the ring opening polymerization, a ring opening polymer or a hydrogenated product thereof with an excellent low birefringence can be obtained. [wherein, at least one of R1 to R4 is a group selected from the group consisting of groups represented by a general formula (1-1) shown below and groups represented by a general formula (1-2) shown below] [wherein, at least one of RA, RB and Z is a group represented by the formula -C(O)O-].

  本发明提供了一种由下图所示通式（1m）表示的新型降冰片烯衍生物。通过对这种降冰片烯衍生物进行开环聚合反应，或在开环聚合反应后进行氢化反应，可获得具有极佳低双折射性的开环聚合物或其氢化产物。 [其中，R1 至 R4 中至少有一个是选自下图所示通式（1-1）所代表的基团和下图所示通式（1-2）所代表的基团所组成的基团。］ [其中，RA、RB 和 Z 中至少有一个是由式 -C(O)O- 所代表的基团]。
• LAMINATED WAVELENGTH PLATE
  申请人：JSR Corporation

  公开号：EP1600799A1

  公开（公告）日：2005-11-30

  A laminated wavelength plate including a cyclic olefin based resin film and a transparent crystal plate having optical anisotropy bonded to each other, wherein an angle defined by an optical axis of the cyclic olefin based resin film and an optical axis of the transparent crystal plate having optical anisotropy falls within the range of from 0 to 90 degrees. The laminated wavelength plate of the invention is a broadband wavelength plate (retardation plate) which is stable against heat, humidity and the like, is effective against plural laser beams having a different wavelength, and can be used as a wavelength plate for optical information recording and reproducing devices.

  一种层叠波长板，包括相互粘合的环状烯烃基树脂薄膜和具有光学各向异性的透明晶体板，其中环状烯烃基树脂薄膜的光轴和具有光学各向异性的透明晶体板的光轴所确定的角度在 0 至 90 度范围内。本发明的层压波长板是一种宽带波长板（延迟板），它对热量、湿度等稳定，对具有不同波长的多束激光有效，可用作光学信息记录和再现设备的波长板。
• WAVE PLATE FOR LASER OPTICAL SYSTEM
  申请人：JSR Corporation

  公开号：EP1691221A1

  公开（公告）日：2006-08-16

  A wavelength plate laser optical system which is a wavelength plate using a stretched and oriented film containing a cyclic olefin based resin, and which has values of the formula (a): Re(λ)/λ (wherein λ, represents a wavelength (nm) of the laser beam; and Re(λ) represents a retardation value (nm) of the laser beam having transmitted through the wavelength plate) against two laser beams having a different wavelength such that the value is ((0.2 to 0.3) + X) for a first laser beam and that the value is ((0.8 to 1.2) + Y) for a second laser beam, respectively (wherein X represents 0 or the number of an integral multiple of 0.5; and Y represents 0 or an integer of 1 or more). It is possible to provide a wavelength plate for optical information recording and reproducing devices, which is excellent in initial characteristics, is hardly affected by the use environment and the manufacturing environment, is excellent in long-term reliability, and is corresponding to two laser beams having a different wavelength.

  一种波长板激光光学系统，它是一种使用含有环烯烃基树脂的拉伸和定向薄膜的波长板，其值如式(a)所示：Re(λ)/λ（其中，λ，表示激光束的波长（纳米）；Re(λ)表示激光束穿过波长板时的延迟值（纳米）），针对两束不同波长的激光束，其值为（（0.其中，X 代表 0 或 0.5 的整数倍；Y 代表 0 或 1 或 1 以上的整数）。这样就有可能提供一种用于光学信息记录和再现设备的波长板，其初始特性优异，几乎不受使用环境和制造环境的影响，长期可靠性极佳，并与具有不同波长的两束激光相对应。