1,3-bis[2-(diphenylphosphoryl)phenoxy]propane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-bis[2-(diphenylphosphoryl)phenoxy]propane
• 英文别名: 1,3-Bis[2-(diphenylphosphoryl)phenoxy]propane；1-diphenylphosphoryl-2-[3-(2-diphenylphosphorylphenoxy)propoxy]benzene
• 化学式: C₃₉H₃₄O₄P₂
• 分子量: 628.644
• InChiKey: LWUQGHBKRYLNLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  45
• 可旋转键数：
  12
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-bis[2-(diphenylphosphoryl)phenoxy]propane 、 cadmium(II) iodide 以 乙腈 为溶剂， 生成 [CdI₂(1,3-bis[2-(diphenylphosphoryl)phenoxy]propane)]
  参考文献：
  名称：

  Complex-forming and ion-selective properties of bis(2-diphenylphosphorylalkyl)phenyl ethers of ethylene glycols. Crystal structures of cadmium complexes

  摘要：

  New complexes of cadmium iodide with 1,3-bis[2-(diphenylphosphoryl)phenoxy]propane [(CdLI2)-I-0], 1,2-bis[2-(diphenylphosphorylethyl)phenoxy]ethane [(CdLI2)-I-1, 2], and 1,8-bis[2-(diphenylphosphorylethyl) phenoxy]-3,6-dioxaoctane [(CdLI2)-I-3, 2] are synthesized and their IR spectra and crystal structures are studied. Electroanalytical characteristics of membranes of ion-selective electrodes based on L-0, L-1,L- 2, L-3,L- 2, and known crown ethers are compared for cations of alkali, alkaline-earth, and transition metals. Ligand L-3,L- 2 is the first podand with terminal diphenylphosphoryl fragments to exhibit selectivity with respect to the cadmium cation.

  DOI：

  10.1134/s0036023617040143