申请人:FUJIWARA Masaki
公开号:US20080108846A1
公开(公告)日:2008-05-08
A process for producing an alkoxycarbonylfluoroalkanesulfonate represented by the formula [1] is provided. This process includes the steps of (a) reacting a halofluoroalkanoate represented by the formula [2], with a sulfinating agent, thereby obtaining an alkoxycarbonylfluoroalkanesulfinate represented by the formula [3]; and (b) reacting the alkoxycarbonylfluoroalkanesulfinate with an oxidizing agent, thereby obtaining the target alkoxycarbonylfluoroalkanesulfonate. Furthermore, it is possible to react the obtained alkoxycarbonylfluoroalkanesulfonate with a monovalent onium salt to conduct a salt exchange, thereby obtaining a alkoxycarbonylfluoroalkanesulfonic acid onium salt represented by the formula [4].
提供了一种制备由公式[1]表示的烷氧羰基氟代烷磺酸盐的方法。这个过程包括以下步骤:(a)使由公式[2]表示的卤氟代烷酸盐与亚磺化剂反应,从而获得由公式[3]表示的烷氧羰基氟代烷亚磺酸盐;以及(b)使烷氧羰基氟代烷亚磺酸盐与氧化剂反应,从而获得目标烷氧羰基氟代烷磺酸盐。此外,可以将获得的烷氧羰基氟代烷磺酸盐与单价阳离子盐进行反应,进行盐交换,从而获得由公式[4]表示的烷氧羰基氟代烷磺酸阳离子盐。