2,4-bis(3-methylbut-2-enyl)phenol | 55824-31-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2,4-bis(3-methylbut-2-enyl)phenol
• 英文别名: 2,4-Bis-(3-methyl-2-butenyl)-phenol；2,4-Diprenyl-phenol；2,4-Bis(3-methylbut-2-en-1-yl)phenol
• CAS: 55824-31-2
• 化学式: C₁₆H₂₂O
• 分子量: 230.35
• InChiKey: HNWKIEJMMGOJSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,4-bis(3-methylbut-2-enyl)phenol 在 platinum on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 反应 20.0h， 生成 2,4-Di-iso-pentyl-phenol
  参考文献：
  名称：

  Secondary metabolite chemistry of the Australian brown alga Encyothalia cliftonii: Evidence for herbivore chemical defence

  摘要：

  Two bis-prenylated phenols have been isolated from the Western Australian brown alga Encyothalia cliftonii Harvey. The structures of these compounds were determined by spectral and chemical methods. The major metabolite, 2,4-bis(3-methylbut-2-enyl)phenol, previously isolated as a minor metabolite from the related alga Perithalia caudata, showed significant feeding deterrence toward the herbivorous sea urchin Tripneustes esculentus (Leske). The minor metabolite is a new compound in which hydration of one of the isopentenyl olefinic bonds has taken place.

  DOI：

  10.1016/s0031-9422(00)90790-8
• 作为产物：
  描述：

  1-氯-3-甲基-2-丁烯 、 苯酚 生成 2,4-bis(3-methylbut-2-enyl)phenol
  参考文献：
  名称：

  Yamada,S. et al., Synthetic Communications, 1975, vol. 5, # 3, p. 181 - 184

  摘要：

  DOI：

文献信息

• The Aluminum Phenoxide-catalyzed Reaction of Phenol with Dienes
  作者：K. C. Dewhirst、F. F. Rust

  DOI：10.1021/jo01038a051

  日期：1963.3
• YAMADA SHIGETOSHI; ONO FUTARA; KATAGIRI TAKAO; TANAKA JUNTARO, NIXON KAGAKU KAJSI, NIRRON KAGAKU KAISNI, J. CHEM. SOS. JAR., CHEM. AND I+
  作者：YAMADA SHIGETOSHI、 ONO FUTARA、 KATAGIRI TAKAO、 TANAKA JUNTARO

  DOI：——

  日期：——
• Yamada,S. et al., Synthetic Communications, 1975, vol. 5, # 3, p. 181 - 184
  作者：Yamada,S. et al.

  DOI：——

  日期：——
• Secondary metabolite chemistry of the Australian brown alga Encyothalia cliftonii: Evidence for herbivore chemical defence
  作者：Vassilios Roussis、Rachel L. King、William Fenical

  DOI：10.1016/s0031-9422(00)90790-8

  日期：1993.8

  Two bis-prenylated phenols have been isolated from the Western Australian brown alga Encyothalia cliftonii Harvey. The structures of these compounds were determined by spectral and chemical methods. The major metabolite, 2,4-bis(3-methylbut-2-enyl)phenol, previously isolated as a minor metabolite from the related alga Perithalia caudata, showed significant feeding deterrence toward the herbivorous sea urchin Tripneustes esculentus (Leske). The minor metabolite is a new compound in which hydration of one of the isopentenyl olefinic bonds has taken place.