1,4-Bis(allylamino)anthracene-9,10-dione | 93184-42-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,4-Bis(allylamino)anthracene-9,10-dione
• 英文别名: 1,4-Bis[(prop-2-en-1-yl)amino]anthracene-9,10-dione；1,4-bis(prop-2-enylamino)anthracene-9,10-dione
• CAS: 93184-42-0
• 化学式: C₂₀H₁₈N₂O₂
• 分子量: 318.375
• InChiKey: LHUYQQLZBQCPGD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,4-二羟基蒽醌 在 potassium carbonate 作用下， 以 二氯甲烷 、 丁酮 为溶剂， 反应 43.0h， 生成 1,4-Bis(allylamino)anthracene-9,10-dione
  参考文献：
  名称：

  Synthesis of unsymmetrical 1,4-bis[(aminoalkyl)amino]anthracene-9,10-diones for antineoplastic evaluation

  摘要：

  DOI：

  10.1021/jo00200a049

文献信息

• MICROWELL ARRAY ARTICLES AND METHODS OF USE
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20160025637A1

  公开（公告）日：2016-01-28

  The disclosure provides microstructured articles and methods useful for detecting an analyte in a sample. The articles include microwell arrays. The articles can be used with an optical system component in methods to detect or characterize an analyte.

  该披露提供了用于在样品中检测分析物的微结构化物品和方法。这些物品包括微孔阵列。这些物品可以与光学系统组件一起使用，用于检测或表征分析物的方法。
• Novel method of producing polyesterified liquid anthraquinone-based colorants
  申请人：——

  公开号：US20040250357A1

  公开（公告）日：2004-12-16

  An inventive blue colorant comprising a chromophore having at least one hydroxy group-terminated polyester chain attached, through a suitable alkylamino linking group (or groups), to the 1-position, the 4-position, or both, of an anthraquinone backbone is provided. Such colorants exhibit excellent amine/base stability and thermal stability, effective colorations, excellent low extraction rates, and high lightfastness levels, particularly when incorporated within certain media and/or on the surface of certain polyurethane substrates. The polyester chain or chains can be conveniently tailored to increase the solubility or compatibility in different types of polyurethane resin precursors thereby permitting the introduction of such excellent coloring chromophores within diverse polyurethane media and/or or diverse polyurethane substrates as well as provides a liquid colorant which facilitates handling. Compositions and articles comprising such inventive colorants are provided as well as methods for producing such inventive colorants.

  提供一种创新的蓝色染料，包括至少一个具有羟基末端的聚酯链的色团，通过适当的烷基氨基连接基（或基团）连接到蒽醌骨架的1位、4位或两者。这种染料表现出优异的胺/碱稳定性和热稳定性，有效的着色效果，出色的低萃取率和高耐光性水平，特别是当它们被包含在某些介质内和/或涂在某些聚氨酯基材表面时。聚酯链可以方便地定制，以增加在不同类型的聚氨酯树脂前体中的溶解性或兼容性，从而允许将这些优秀的着色色团引入各种聚氨酯介质和/或不同聚氨酯基材中，并提供一种便于处理的液体染料。还提供包含这种创新染料的组合物和制备这种创新染料的方法。
• Polyoxyalkylene amino alcohols and polyoxyalkylene amino 1,3-dioxanes and 1,3-dioxolanes
  申请人：MILLIKEN RESEARCH CORPORATION

  公开号：EP0322110A2

  公开（公告）日：1989-06-28

  Primary amino polyoxyalkylene 1,3-dioxane or 1,3-dioxolane compounds are provided of the formula: wherein R and R₁ are independently selected from hydrogen or a lower alkyl group; R₂ and R₃ are independently selected from hydrogen, phenyl, or lower alkyl groups; R₄ is selected from hydrogen or a lower alkyl group; x is 0 or 1; N and M are each integers of from 1 to about 100 and the sum of N an M is from 2 to about 100; also disclosed are polyoxyalkylene amino alcohol compounds which may be derived from the compounds of Formula I above having the formula: wherein R, R₁, R₄, x, N and M all have the values given above. wherein R, R₁, R₄, x, N and M all have the values given above. b) reacting said remaining free hydroxy groups with an alkylene oxide selected from ethylene oxide, propylene oxide, or butylene oxide under basic conditions to form a polyoxyalkylene-substituted 1,3-dioxane or 1,3-dioxolane having hydroxy end group functionalities; and having the values given above.

  提供了式如下的伯氨基聚氧亚烷基 1，3-二氧杂环戊烷或 1，3-二氧戊环化合物： 其中R和R₁独立地选自氢或低级烷基；R₂和R₃独立地选自氢、苯基或低级烷基；R₄选自氢或低级烷基；x为0或1；N和M各自为1至约100的整数，且N和M之和为2至约100；还公开了聚氧亚烷基氨基醇化合物，该化合物可由上述式I化合物衍生而来，其式如下： 其中 R、R₁、R₄、x、N 和 M 均具有上述值。 其中 R、R₁、R₄、x、N 和 M 均具有上式所给的值。 b) 在碱性条件下，将所述剩余的游离羟基与选自环氧乙烷、环氧丙烷或环氧丁 烷的环氧烷反应，形成具有羟基端基官能团的聚氧亚烷基取代的 1，3-二氧杂环戊 烷或 1，3-二氧戊环，并具有上式所给的值。
• Process for preparing polyurethane resins colored with Anthraquinone colorants and products produced thereby
  申请人：MILLIKEN RESEARCH CORPORATION

  公开号：EP0348024A2

  公开（公告）日：1989-12-27

  A process for coloring polyurethane resins made by a polyaddition reaction of a polyol and an isocyanate is provided, which comprises adding to the reaction mixture before or during the polyaddition reaction a reactive coloring agent suitable for incorporation in the resin with the formation of covalent bonds, said coloring agent having the formula: in which R₁ and R₂ are independently selected from an alkyl group having from 1 to about 12 carbon atoms, X is --CH₂--, a and a′ are integers from 1 to about 6, and Y and Y′ are independently selected from polymeric units of hydroxy alkylenes or alkylene oxide monomers selected from ethylene oxide, propylene oxide, butylene oxide, cyclohexene oxide, or glycidol, b and b′ are independently either 0 or 1, and Z and Z′ are reactive groups independently selected from ―OH, ―NH₂, or ―SH.

  本发明提供了一种通过多元醇和异氰酸酯的加成反应制得的聚氨酯树脂的着色工艺，该工艺包括在加成反应前或反应过程中向反应混合物中加入一种活性着色剂，该着色剂适于通过形成共价键掺入树脂中，所述着色剂具有以下式子： 其中 R₁ 和 R₂ 独立地选自具有 1 至约 12 个碳原子的烷基，X 为--CH₂--，a 和 a′ 为 1 至约 6 的整数，Y 和 Y′ 独立地选自羟基亚烷基或环氧亚烷基单体的聚合单元，这些单体选自环氧乙烷环氧丙烷、环氧丁烯、环己烯或缩水甘油，b 和 b′ 独立地为 0 或 1，Z 和 Z′ 是独立选自 -OH、-NH₂ 或 -SH 的反应基团。
• Water-reducible dye compositions
  申请人：MORTON INTERNATIONAL, INC.

  公开号：EP0625552A1

  公开（公告）日：1994-11-23

  Water-immiscible dyes are mixed with citrus solvents and non-ionic surfactants to form a water-reducible true dye solution containing at least 35 wt% of the water-immiscible dye. The dye solution is dispersible in water and infinitely reducible.

  将不溶于水的染料与柑橘类溶剂和非离子表面活性剂混合，形成可还原的水溶性染料溶液，其中至少含有 35 wt%的不溶于水的染料。该染料溶液可在水中分散，并可无限还原。