1,2-bis(diphenylphosphino)cyclohexane | 63708-53-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(diphenylphosphino)cyclohexane
• 英文别名: 1,2-di(diphenylphosphino)cyclohexane；(2-diphenylphosphanylcyclohexyl)-diphenylphosphane
• CAS: 63708-53-2
• 化学式: C₃₀H₃₀P₂
• 分子量: 452.516
• InChiKey: YLDJNDYRGPTCKV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  32
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Chiral diphosphines via 2,3 -sigmatropic rearrangement.Application in asymmetric transition metal catalysis
  申请人：PPG-Sipsy S.C.A.

  公开号：EP1182205A1

  公开（公告）日：2002-02-27

  The present invention refers to Chiral diphosphines selected from a) diphosphines corresponding to the formula wherein R1 - R4 are each independently selected from substituted and unsubstituted hydrocarbyl groups, b) diphosphines corresponding to the formula wherein R1 - R4 are each independently selected from substituted and unsubstituted hydrocarbyl groups with the proviso that if R1 and R2 is phenyl at least one of R3 and R4 is different from phenyl c) diphosphines corresponding to the formula wherein R1 - R4 are each independently selected from substituted and unsubstituted hydrocarbyl groups and R5 and R6 are each independently selected from the group consisting of hydrogen, alkyl and residues of protecting groups, whereby R6 and R5 taking together may be an divalent substituent thereby forming a bicyclus, to a method of making same, to a method for preparing a chiral precursor suitable for making the new chiral diphosphines, to transition metal complexes comprising the chiral diphosphines of the present invention, and to the use of either the chiral diphosphines or their transition metal complexes in asymmetric synthesis.

  本发明涉及手性二膦化合物，所选的二膦化合物包括： a）符合以下式子的二膦化合物，其中R1-R4各自独立地选自取代和未取代的碳氢化合物基团； b）符合以下式子的二膦化合物，其中R1-R4各自独立地选自取代和未取代的碳氢化合物基团，但如果R1和R2是苯基，则R3和R4中至少有一个不同于苯基； c）符合以下式子的二膦化合物，其中R1-R4各自独立地选自取代和未取代的碳氢化合物基团，而R5和R6各自独立地选自氢、烷基和保护基残基的群，其中R6和R5可以一起取代成为一个双价取代基团，从而形成一个双环。本发明还涉及制备该手性二膦化合物的方法、制备适用于制备新手性二膦化合物的手性前体的方法、包括本发明的手性二膦化合物的过渡金属配合物，以及在不对称合成中使用手性二膦化合物或其过渡金属配合物的用途。
• Preparation of alternating olefin/carbon monoxide copolymers by means of a heterogeneous supported catalyst
  申请人：ENICHEM S.p.A.

  公开号：EP0559288A1

  公开（公告）日：1993-09-08

  A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by: (a) Pd(O₂CNEt₂)₂(NHET₂)₂ supported on a solid carrier preferably constituted by hydroxylated silica, (b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorous atoms capable of linking to Pd atom by dative bonds, (c) a mineral or organic acid. Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).

  一种可用于制备烯烃/一氧化碳（CO）交替共聚物的催化剂由以下部分组成： (a) Pd(O₂CNEt₂)₂(NHET₂)₂，支撑在最好由羟基二氧化硅构成的固体载体上、 (b) 含有一个或两个氮原子或磷原子并能通过二价键与钯原子连接的一价或 二价配体、 (c) 矿物酸或有机酸。 本发明公开了催化剂的制备方法，以及所述催化剂在乙烯（C2）和/或其他烯烃与一氧化碳（CO）交替共聚中的用途。
• Heterogeneous catalyst for preparing alternating olefin/carbon monoxide copolymers
  申请人：ENICHEM S.p.A.

  公开号：EP0559289A1

  公开（公告）日：1993-09-08

  A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by: (a) Pd(O₂CNEt₂)₂(NHEt₂)₂ supported on a solid carrier preferably constituted by hydroxylated silica, (b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorous atoms capable of linking to Pd atom by dative bonds, (c) NOBF₄. Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).

  一种可用于制备烯烃/一氧化碳（CO）交替共聚物的催化剂由以下部分组成： (a) Pd(O₂CNEt₂)₂(NHEt₂)₂，支撑在最好由羟基二氧化硅构成的固体载体上、 (b) 含有一个或两个氮原子或磷原子并能通过二价键与钯原子连接的一价或 二价配体、 (c) NOBF₄。 本发明公开了催化剂的制备方法，以及所述催化剂在乙烯（C2）和/或其他烯烃与一氧化碳（CO）交替共聚中的用途。
• Catalytic system and process for copolymerizing carbon monoxide with one or more olefins
  申请人：ENICHEM S.p.A.

  公开号：EP0560455A1

  公开（公告）日：1993-09-15

  A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by: (a) at least one salt of a metal of Group IB of the Periodic System, (b) a mono or bidentate ligand base containing one or two nitrogen or phosphorus atoms capable of linking to the metal atom by means of dative bonds, (c) a mineral or organic oxidizer agent. Also disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).

  一种可用于制备烯烃/一氧化碳（CO）交替共聚物的催化剂由以下部分组成： (a) 周期系 IB 族金属的至少一种盐、 (b) 含有一个或两个氮或磷原子的单或双齿配位基，能通过配位键与金属原子连接、 (c) 一种矿物或有机氧化剂。 此外，还公开了催化剂的制备方法，以及所述催化剂在乙烯（C2）和/或其他烯烃与一氧化碳（CO）交替共聚中的用途。
• Novel homogeneous catalytic system and process for copolymerizing olefins with carbon monoxide
  申请人：ENICHEM S.p.A.

  公开号：EP0560456A1

  公开（公告）日：1993-09-15

  A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by: (a) at least one salt of a metal of Group IB of the Periodic System, (b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorus atoms capable of linking to the copper, silver or gold atom by means of dative bonds, (c) a mineral or organic acid. Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide.

  一种可用于制备烯烃/一氧化碳（CO）交替共聚物的催化剂由以下物质构成： (a) 周期系 IB 族金属的至少一种盐、 (b) 含有一个或两个氮或磷原子的单齿或双齿配体，该配体可通过配位键与铜、银或金原子连接、 (c) 矿物酸或有机酸。 本发明公开了催化剂的制备方法以及上述催化剂在乙烯（C2）和/或其他烯烃与一氧化碳交替共聚中的用途。