2-(12-aminotridecyl)-pyrrolidine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: 2-(12-aminotridecyl)-pyrrolidine
• 英文别名: 2-(12-Aminotridecyl)pyrrolidine；13-pyrrolidin-2-yltridecan-2-amine
• 化学式: C₁₇H₃₆N₂
• 分子量: 268.486
• InChiKey: LNAVQMDAZGLAPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  19
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  α-溴-2,3,4,5,6-五氟甲基苯酸酯 、 2-(12-aminotridecyl)-pyrrolidine 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 生成
  参考文献：
  名称：

  Alkaloids of the Mexican Bean Beetle, Epilachna varivestis (Coccinellidae)

  摘要：

  Two novel alkaloids, 2-(12-aminotridecyl)-pyrrolidine and its 1-(2-hydroxyethyl) derivative, are characterized from extracts of adult Mexican bean beetles. These pyrrolidines, together with a previously identified homotropane alkaloid, euphococcinine, account for 90% of the alkaloids present in this beetle. A number of piperidine derivatives are also identified as minor components. The total mixture represents the most complex bouquet of alkaloids reported hitherto from any coccinellid beetle.

  DOI：

  10.1016/0040-4020(93)80019-p

文献信息

• Alkaloids of the Mexican Bean Beetle, Epilachna varivestis (Coccinellidae)
  作者：Athula B. Attygalle、Shang-Cheng Xu、Kevin D. McCormick、Jerrold Meinwald、Curtis L. Blankespoor、Thomas Eisner

  DOI：10.1016/0040-4020(93)80019-p

  日期：——

  Two novel alkaloids, 2-(12-aminotridecyl)-pyrrolidine and its 1-(2-hydroxyethyl) derivative, are characterized from extracts of adult Mexican bean beetles. These pyrrolidines, together with a previously identified homotropane alkaloid, euphococcinine, account for 90% of the alkaloids present in this beetle. A number of piperidine derivatives are also identified as minor components. The total mixture represents the most complex bouquet of alkaloids reported hitherto from any coccinellid beetle.